Copper;methyl pyridine-2-carboximidate;dichloride | 26117-67-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Copper;methyl pyridine-2-carboximidate;dichloride
• CAS: 26117-67-9
• 化学式: C₇H₈Cl₂CuN₂O
• 分子量: 270.605
• InChiKey: LLPUHHWDYLOMAZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.94
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  46
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基吡啶亚胺甲酯 、 copper dichloride 以 甲醇 为溶剂， 生成 Copper;methyl pyridine-2-carboximidate;dichloride
  参考文献：
  名称：

  Methanolysis of pyridine-2-carbonitrile in the coordination sphere of copper(II), cobalt(II) and nickel(II). The structure of [Ni(o-methylpyridine-2-carboximidate)3]Br2·4H2O

  摘要：

  The reaction of pyridine-2-carbonitrile with copper(II), cobalt(II) and nickel(II) salts in methanol solution led to the formation of solid complexes containing O-methylpyridine-2-carboximidate as a ligand (L). Seventeen compounds with general formulae [MX(2)L], [MXL(2)]X, [MX(2)L(2)] Or [ML(3)]X(2), where X = Br-, Cl-, NCS-, ClO4- and M = Cu-II, Co-II, Ni-II, have been obtained under various reaction conditions. Their stereochemistry and the mode of ligand coordination have been determined by spectral, magnetic and conductometric measurements. The crystal structure of [Ni(O-methylpyridine-2-carboximidate)(3)]Br-2 . 4H(2)O was determined by X-ray diffraction techniques. The influence of the metal(II) atom on the composition and the stereochemistry of solid complexes is briefly discussed.

  DOI：

  10.1016/0277-5387(94)00471-p

文献信息

• Methanolysis of pyridine-2-carbonitrile in the coordination sphere of copper(II), cobalt(II) and nickel(II). The structure of [Ni(o-methylpyridine-2-carboximidate)3]Br2·4H2O
  作者：M. Jamnický、P. Segl'a、M. Koman

  DOI：10.1016/0277-5387(94)00471-p

  日期：1995.7

  The reaction of pyridine-2-carbonitrile with copper(II), cobalt(II) and nickel(II) salts in methanol solution led to the formation of solid complexes containing O-methylpyridine-2-carboximidate as a ligand (L). Seventeen compounds with general formulae [MX(2)L], [MXL(2)]X, [MX(2)L(2)] Or [ML(3)]X(2), where X = Br-, Cl-, NCS-, ClO4- and M = Cu-II, Co-II, Ni-II, have been obtained under various reaction conditions. Their stereochemistry and the mode of ligand coordination have been determined by spectral, magnetic and conductometric measurements. The crystal structure of [Ni(O-methylpyridine-2-carboximidate)(3)]Br-2 . 4H(2)O was determined by X-ray diffraction techniques. The influence of the metal(II) atom on the composition and the stereochemistry of solid complexes is briefly discussed.