benzene-1,2-dithiolate;gold(3+);1,2,3,4,5-pentafluorobenzene-6-ide;2-triphenylphosphaniumylsulfanylbenzenethiolate | 172842-12-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzene-1,2-dithiolate;gold(3+);1,2,3,4,5-pentafluorobenzene-6-ide;2-triphenylphosphaniumylsulfanylbenzenethiolate
• CAS: 172842-12-5
• 化学式: C₃₆H₂₃AuF₅PS₄
• 分子量: 906.775
• InChiKey: GDVNZVHFKXRFSX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (PPN)2[Zn(1,2-benzenedithiolate)2] 以 乙醚 、 二氯甲烷 为溶剂， 生成 benzene-1,2-dithiolate;gold(3+);1,2,3,4,5-pentafluorobenzene-6-ide;2-triphenylphosphaniumylsulfanylbenzenethiolate
  参考文献：
  名称：

  Synthesis and Reactivity of Trinuclear Gold(III) Dithiolate Complexes. X-ray Structure of [Au(C6F5)(S2C6H4)]3 and [Au(C6F5)(S2C6H4)(SC6H4SPPh3)]

  摘要：

  Q(2)[Zn(S-S)(2)] or [SnMe(2)(S-S)] (Q = NBu(4) or PPN, S-S = S2C6H4, S2C6H3CH3, or C3S5 (dmit)) reacts with trans-[Au(C6F5)Cl-2(tht)] affording trinuclear species [Au(C6F5)(S-S)](3) (1-3). When [AuX(3)(tht)] (X = Cl or Br) are used instead, [AuBr(S-S)], (4-6) and [AuCl(dmit)](n) (7) are obtained. Complex 1 further reacts with PPh(3) to give [Au(C6F5)(S2C6H4)(SC(6)H(4)SPPh(3))]. Complexes 1-3 react with neutral (pyridine) or anionic (Cl, Br, or SCN) ligands affording [Au(C6F5)(S-S)(py)] (9a-c) or Q[Au(C6F5)(S-S)X] (10a-c-12a-c) complexes. The structures of 1 and 8 have been established by X-ray crystallography. Complex 1 shows a six-membered Au3S3 ring which adopts a chair configuration and shows a gold-gold distance of 3.515 Angstrom. Complex 8 is a mononuclear square-planar gold(III) complex with a new SC(6)H(4)SPPh(3) thiolate ligand, the P-S bond length being 2.058(5) Angstrom.

  DOI：

  10.1021/om00012a021