(C9H7)Mo(η(3)-C9H7)(CO)2 | 168556-25-0

• 英文名称: (C9H7)Mo(η(3)-C9H7)(CO)2
• 英文别名: [Mo(η(5)-Ind)(η(3)-Ind)(CO)2]；[(η5-C9H7)Mo(η3-C9H7))(CO)2]
• CAS: 168556-25-0
• 化学式: C₂₀H₁₄MoO₂
• 分子量: 382.27
• InChiKey: NDYQDSRXIZTTMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (C9H7)Mo(η(3)-C9H7)(CO)2 、 trityl tetrafluoroborate 以 二氯甲烷 为溶剂， 以89%的产率得到[Ind2Mo(CO)2][BF4]2
  参考文献：
  名称：

  New Synthetic Pathway to Mono- and Bis-indenyl Complexes of Molybdenum(IV)

  摘要：

  The complex IndMoCl(3)(CO)(2) (Ind = eta(5)-C9H7) has been synthesized by the reaction of IndMo-(eta(3)-C3H5)(CO)(2) with HCl gas in dichloromethane at 25 degrees C. Thermal decarbonylation of IndMoCl(3)(CO)(2) in chloroform gives paramagnetic IndMoCl(3) (mu(eff) = 1.48 mu(B)). A consistent stepwise route to bis-indenyl derivatives of molybdenum is available upon treatment of IndMoCl(3)(CO)(2) with Kind in THF at low temperature. The complex IndMo(eta(3)-Ind)(CO)(2) is obtained in high yield and opens a convenient entry into bis-indenyl molybdenum chemistry. The reaction of IndMo(eta(3)-Ind)(CO)(2) with Ph3CBF4, in CH2Cl2, yields [Ind(2)Mo(CO)(2)][BF4](2). Solvolysis of [Ind(2)Mo(CO)(2)][BF4](2) in acetonitrile affords [Ind(2)Mo(CO)(NCMe)][BF4](2) and [Ind(2)-Mo(NCMe)(2)][BF4](2). The reaction of [Ind(2)Mo(NCMe)(2)][BF4](2) with [Bu4N][S2CNEt2] forms the dithiocarbamate complex [Ind(2)Mo(S2CNEt2)][BF4]. The molecular structures of IndMo(eta(3)-Ind)(CO)(2) and [Ind(2)Mo(S2CNEt2)][BF4] have been determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om9805178
• 作为产物：
  描述：

  [(η(5)-indenyl)Mo(η(3)-C3H5)(CO)2] 、 茚 在 HBF₄ * Et₂O 、 NEt₃ 作用下， 以 二氯甲烷 为溶剂， 以73%的产率得到(C9H7)Mo(η(3)-C9H7)(CO)2
  参考文献：
  名称：

  Ascenso, José R.; De Azevedo, Cristina G.; Gonçalves, Isabel S., Organometallics, 1995, vol. 14, # 8, p. 3901 - 3919

  摘要：

  DOI：