| 134584-83-1

• CAS: 134584-83-1
• 化学式: C₁₀BiBrMn₂O₁₀
• 分子量: 678.864
• InChiKey: VXMVXIIJPGGXCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  溴化铋 、 sodium-manganese pentacarbonyl 以 四氢呋喃 为溶剂， 以39%的产率得到
  参考文献：
  名称：

  Bismuth complexes containing Mn(CO)5 and Re(CO)5 fragments. Synthetic studies and structural characterisation by solid- and solution-state extended X-ray absorption fine structure spectroscopy

  摘要：

  The reaction between BiCl3 and 3 equivalents of Na[Re(CO)5] affords the complex [Bi{Re(CO)5}3] 2, which is compared with the known [Bi{Mn(CO)5}3] 1. The dimetal complexes [BiCl{M(CO)5}2] (M = Mn, 3 or Re, 4) were prepared from reactions between BiCl3 and 2 equivalents of the corresponding metal carbonylate anion. The reaction between compound 1 or 2 and 0.5 equivalent of BiCl3 affords 3 and 4 respectively whilst the reaction between either 3 and 1 equivalent of BiCl3 or between BiCl3 and 1 equivalent of Na[Mn(CO)5] affords a compound formulated as [BiCl2{Mn-(CO)5}] 5. The syntheses of the bromide and iodide complexes [BiX{Mn(CO)5}2] (X = Br, 6 or 1, 7) are also described. In addition, solution infrared studies are reported on the time- and concentration-dependent decomposition of 3 in tetrahydrofuran (thf) together with details of a number of reactivity studies involving 3. Analysis of Bi-L(III) edge and Mn-K edge extended X-ray absorption fine structure spectra for compounds 3 and 4 in solid and solution phases show evidence for oligo- or polymerisation through Bi...Cl interactions in the solids. In a thf solution of 3 these interactions are disrupted, and the monomeric species formed shows co-ordination of solvent to bismuth.

  DOI：

  10.1039/dt9910000669