cyclopenta-1,3-diene;tetraphenylboranuide;triethylphosphane;zirconium(4+) | 259881-44-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cyclopenta-1,3-diene;tetraphenylboranuide;triethylphosphane;zirconium(4+)
• CAS: 259881-44-2
• 化学式: C₂₁H₃₀PZr*C₂₄H₂₀B
• 分子量: 723.901
• InChiKey: QFLNDFSCJCCKRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cyclopenta-1,3-diene;tetraphenylboranuide;zirconium(4+) 、 三乙基膦 以 二氯甲烷 为溶剂， 生成 cyclopenta-1,3-diene;tetraphenylboranuide;triethylphosphane;zirconium(4+)
  参考文献：
  名称：

  Carbon monoxide and tertiary phosphines as ligands in cyclopentadienyl derivatives of Group 4 elements in high oxidation state

  摘要：

  The titanocene dicarbonyl dication [TiCp2(CO)(2)][BPh4](2), (1) has been obtained in toluene under carbon monoxide by double protonation of TiCp4 with [(NHBu3)-Bu-n][BPh4] or by two-electron oxidation of TiCp2(CO)(2) with [FeCp2][BPh4]. Protonation reactions on ZrCp4 and HfCp4 proceed with elimination of 1 mol of cyclopentadiene independently on the ammonium salt/MCp4 molar ratio used. By this route the high electrophilic, solvent-free [ZrCp3](+) cation has been isolated and characterized by IR, H-1-NMR and elemental analysis. In the case of hafnium, the isolation has not been possible; nevertheless, in the presence of CO a rare example of a carbonyl derivative of hafnium(IV), [HfCp3(CO)][BPh4], has been isolated and characterized. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00233-8