2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(tosylamido)phthalocyaninatonickel(II) | 954371-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(tosylamido)phthalocyaninatonickel(II)
• CAS: 954371-14-3
• 化学式: C₈₂H₁₀₂N₁₀NiO₄S₈
• 分子量: 1606.99
• InChiKey: XNAANEGADSSFFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-dicyano-4,5-bis(hexylthio)benzene 、 nickel dichloride 、 N,N’-(4,5-二氰基-1,2-亚苯基)双(4-甲基苯磺酰胺) 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 further solvent(s) 为溶剂， 以8%的产率得到2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(tosylamido)phthalocyaninatonickel(II)
  参考文献：
  名称：

  Synthesis and characterization of liquid crystalline unsymmetrically substituted phthalocyanines

  摘要：

  The synthesis of unsymmetrically substituted phthalocyanines bearing two p-tolyl-sulfonyl (tosyl)amido and six alkylthio moieties was achieved by cyclotetramerisation of two different phthalonitrile derivatives, namely 1,2-di(alkylthio)-4,5-dicyanobenzene and 4,5-dicyano-N,N'-ditosyl-o-phenylen(diamine in the presence of an anhydrous metal salt and strong base. The new compounds were characterized by elemental analyses, UV/Vis, IR, NMR and mass spectra. The mesogenic properties of these new materials were studied by differential scanning calorimetry (DSC) and polarizing optical microscopy. The mesogenic properties of these compounds were compared to that of their symmetric analogous, octaalkythia substituted plithalocyanine derivatives. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.06.017