N,N'-di(2,6-diisopropylphenyl)-1,6,11,16-tetra[4-(1,1,3,3-tetramethyl-butyl)phenoxy]quaterrylene-3,4:13,14-tetracarboxylic acid diimide | 333304-54-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-di(2,6-diisopropylphenyl)-1,6,11,16-tetra[4-(1,1,3,3-tetramethyl-butyl)phenoxy]quaterrylene-3,4:13,14-tetracarboxylic acid diimide
• 英文别名: 2,13-Bis[2,6-bis(1-methylethyl)phenyl]-5,10,16,21-tetrakis[4-(1,1,3,3-tetramethylbutyl)phenoxy]anthra[9a(2)a(2),1a(2)a(2),2a(2)a(2):6,5,10;10a(2)a(2),5a(2)a(2),6a(2)a(2):6a(2),5a(2),10a(2)]dianthra[2,1,9-def:2a(2),1a(2),9a(2)-d'e'fa(2)]diisoquinoline-1,3,12,14(2H,13H)-tetrone；11,30-bis[2,6-di(propan-2-yl)phenyl]-15,34,42,44-tetrakis[4-(2,4,4-trimethylpentan-2-yl)phenoxy]-11,30-diazatridecacyclo[22.14.2.22,5.26,9.225,28.03,20.04,17.07,16.08,13.021,39.026,35.027,32.036,40]hexatetraconta-1(39),2,4,6(44),7,9(43),13,15,17,19,21,23,25(42),26,28(41),32,34,36(40),37,45-icosaene-10,12,29,31-tetrone
• CAS: 333304-54-4
• 化学式: C₁₂₄H₁₃₀N₂O₈
• 分子量: 1776.4
• InChiKey: CWUAUBJQQWLJFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  36.2
• 重原子数：
  134
• 可旋转键数：
  26
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N,N'-di(2,6-diisopropylphenyl)-1,6,11,16-tetra[4-(1,1,3,3-tetramethyl-butyl)phenoxy]quaterrylene-3,4:13,14-tetracarboxylic acid diimide 在 氢氧化钾 、 叔丁醇 、 水 、 溶剂黄146 作用下， 以 叔丁醇 为溶剂， 反应 11.33h， 以10%的产率得到N-(2,6-diisopropylphenyl)-1,6,11,16-tetra[4-(1,1,3,3-tetramethyl-butyl)phenoxy]quaterrylene-3,4:13,14-tetracarboxylic acid monoimide monoanhydride
  参考文献：
  名称：

  WO2006/117383

  摘要：

  公开号：

文献信息

• CHROMOPHORIC COMPOSITIONS
  申请人：BASF SE

  公开号：EP3067216A1

  公开（公告）日：2016-09-14

  The present invention relates to chromophoric compositions, in particular to compositions containing as chromophore an IR absorbing compound and specific stabilizing compounds which prevent the oxidative degradation of the chromophore. Further aspects of the invention are a printing ink containing an IR absorbing chromophore and said specific stabilizing compounds, a security document comprising a substrate and the hardened printing ink and the use of the specific compounds as stabilizers for chromophores in an oxidative environment.

  本发明涉及发色组合物，特别是含有红外吸收化合物作为发色团和防止发色团氧化降解的特定稳定化合物的组合物。本发明的其他方面包括：一种含有红外吸收发色团和所述特定稳定化合物的印刷油墨；一种由基材和硬化印刷油墨组成的防伪文件；以及在氧化环境中使用特定化合物作为发色团的稳定剂。
• USE OF RYLENE DERIVATIVES AS ACTIVE COMPONENTS IN SOLAR CELLS AND PHOTODETECTORS
  申请人：Pschirer Neil Gregory

  公开号：US20100207072A1

  公开（公告）日：2010-08-19

  The present invention relates to the use of compounds of the general formula (I) in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (x1), (x2) or (x3) both are each a —CWWM radical; Y one of the two radicals is either a radical of the formula (y1) -L-NR 1 R 2 (y1) or a radical of the formula (y2) -L-Z—R 3 (y2) and the other radical is hydrogen; are joined to one another with formation of a six-membered ring to give a radical of the formula (y3) or (y4) or both are hydrogen; W are each independently O or S; W′ is O, S or N—R′, with the proviso that at least one of the variables W or W in the general formula I is defined as S; R, P, B, A, D, M, L, Z, R 1 , R 2 , R 3 and R′ are each defined as specified in the description; m is 1, 2, 3 or 4; n is 0, 2 or 4 when m=1, 2 or 3; is 0, 2, 4 or 6 when m=4; p is 0, 2 or 4 when m=1, 2 or 3, where n+p=0, 2 or 4; is 0, 2, 4 or 6 when m=4, where n+p=0, 2, 4 or 6, as active materials in solar cells or photodetectors. The present invention further relates to the use of mixtures comprising, as components, K1) compounds of the general formula (I) as electron donors or electron acceptors and K2) one or more compounds which, with respect to component K1, act correspondingly as electron acceptors or electron donors for producing photoactive layers for solar cells or photodetectors. In addition, the present invention relates to the use of compounds of the general formula (I) as photosensitizers in solar cells or photodetectors. Moreover, the present invention relates to solar cells and photodetectors which comprise compounds of the formula (I) or the aforementioned mixtures, and also to compounds of the general formula (I) and the aforementioned mixtures.
• US8083971B2
  申请人：——

  公开号：US8083971B2

  公开（公告）日：2011-12-27
• [DE] VERWENDUNG VON RYLENDERIVATEN ALS AKTIVE KOMPONENTEN IN SOLARZELLEN UND PHOTODETEKTOREN<br/>[EN] USE OF RYLENE DERIVATIVES AS ACTIVE COMPONENTS IN SOLAR CELLS AND PHOTODETECTORS<br/>[FR] UTILISATION DE DERIVÉS DE RYLÈNE EN TANT QUE COMPOSANTS ACTIFS DANS DES CELLULES SOLAIRES ET DES PHOTODÉTECTEURS
  申请人：BASF SE

  公开号：WO2009013258A1

  公开（公告）日：2009-01-29

  Die vorliegende Erfindung betrifft Verbindungen der allgemeinen Formel (I) und ihre Verwendung als aktive Materialien in Solarzellen und Photodetektoren. Die Variablen in der Formel (I) sind in der Spezifikation definiert. Unter anderem umfasst die Formel (I) das folgende Beispiel.