{Zn(4,6-dimethylpyrimidine-2-thionate)2(pyridine)} | 153882-99-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: {Zn(4,6-dimethylpyrimidine-2-thionate)2(pyridine)}
• CAS: 153882-99-6
• 化学式: C₁₇H₁₉N₅S₂Zn
• 分子量: 422.893
• InChiKey: VRZHHSSQCYAXBF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,6-二甲基-2-巯基嘧啶 、 锌 在 pyridine 作用下， 以 乙腈 为溶剂， 生成 {Zn(4,6-dimethylpyrimidine-2-thionate)2(pyridine)}
  参考文献：
  名称：

  Electrochemical synthesis of zinc(II) complexes of 4,6-dimethylpyrimidine-2-thione: The crystal structure of pyridine-bis(4,6-dimethylpyrimidine-2-thiolato)zinc(II)

  摘要：

  Electrochemical oxidation of zinc in a solution of 4,6-dimethylpyrimidine-2-thione (4,6-Me(2)pymtH) in acetonitrile afforded the compound [Zn(4,6-Me(2)pymt)(2)]. When pyridine (py), 1,10-phenanthroline (phen) or 2,2-bipyridine (bipy) were added to the electrolytic phase [Zn(4,6-Me(2)pymt)(2)py], [Zn(4,6-Me(2)pymt)(2)phen] or [Zn(4,6-Me(2)pymt)(2)bipy] were obtained. The crystal structure of pyridine-bis(4,6-dimethylpyrimidine-2-thio-lato)zinc(II) was determined; the zinc atom has distorted trigonal bipyramidal geometry. The IR and H-1 and C-13 NMR spectra of the complexes are discussed and related to their structures.

  DOI：

  10.1016/s0277-5387(00)86603-6