[Ru(η(6)-C6H6)(N,N',O-tris(2-pyridyl)methanolate)](hexafluorophosphate) | 254876-65-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ru(η(6)-C6H6)(N,N',O-tris(2-pyridyl)methanolate)](hexafluorophosphate)
• 英文别名: benzene;ruthenium(2+);tripyridin-2-ylmethanolate;hexafluorophosphate
• CAS: 254876-65-8
• 化学式: C₂₂H₁₈N₃ORu*F₆P
• 分子量: 586.439
• InChiKey: BTPVCOQHUQNBRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二(氰基苯)二氯化钯 、 [Ru(η(6)-C6H6)(N,N',O-tris(2-pyridyl)methanolate)](hexafluorophosphate) 以 乙醇 为溶剂， 以29%的产率得到[Ru(η(6)-C6H6)(tris(2-pyridyl)methanolate)PdCl2](hexafluorophosphate)
  参考文献：
  名称：

  A heteronuclear compound of ruthenium and silver containing bridging tris(pyridyl)methanoate ligands

  摘要：

  The reaction of [{Ru(eta(6)-C6H6)Cl(mu-Cl)}(2)] with Py3COH in ethanol results in the formation of the cation [Ru(eta(6)-C6H6)(N,N',O, -(C5H4N)(3)CO)](+) which is isolated as its hexafluorphosphate salt 1. The cation acts as a ligand towards other transition metal ions. With Ag+ the hetero-trinuclear complex [{Ru(eta(6)-C6H6)((C5H4N)(3)CO)}(2)Ag][PF6](3) 2 is formed, while reaction with [Pd(PhCN)(2)Cl-2] gives the bimetallic [Ru(eta(6)-C6H6)((C5H4N)(3)CO)PdCl2] [PF6] 3. Both compounds were fully characterised by spectroscopic methods and the trinuclear complex was additionally characterised by X-ray diffraction. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00213-2
• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 ammonium hexafluorophosphate 、 三(2-吡啶基)甲基醇 以 乙醇 为溶剂， 以62%的产率得到[Ru(η(6)-C6H6)(N,N',O-tris(2-pyridyl)methanolate)](hexafluorophosphate)
  参考文献：
  名称：

  A heteronuclear compound of ruthenium and silver containing bridging tris(pyridyl)methanoate ligands

  摘要：

  The reaction of [{Ru(eta(6)-C6H6)Cl(mu-Cl)}(2)] with Py3COH in ethanol results in the formation of the cation [Ru(eta(6)-C6H6)(N,N',O, -(C5H4N)(3)CO)](+) which is isolated as its hexafluorphosphate salt 1. The cation acts as a ligand towards other transition metal ions. With Ag+ the hetero-trinuclear complex [{Ru(eta(6)-C6H6)((C5H4N)(3)CO)}(2)Ag][PF6](3) 2 is formed, while reaction with [Pd(PhCN)(2)Cl-2] gives the bimetallic [Ru(eta(6)-C6H6)((C5H4N)(3)CO)PdCl2] [PF6] 3. Both compounds were fully characterised by spectroscopic methods and the trinuclear complex was additionally characterised by X-ray diffraction. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00213-2