(S)-Methyl-phosphonic acid methyl ester phenyl ester | 70741-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (S)-Methyl-phosphonic acid methyl ester phenyl ester
• 英文别名: [Methoxy(methyl)phosphoryl]oxybenzene
• CAS: 70741-69-4
• 化学式: C₈H₁₁O₃P
• 分子量: 186.147
• InChiKey: DKGFJWDKTSVYKE-LBPRGKRZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲醇 、 alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 作用下， 反应 24.0h， 以53%的产率得到(S)-Methyl-phosphonic acid methyl ester phenyl ester
  参考文献：
  名称：

  Convenient Procedure for the Preparation of Optically Active Phosphonates Using the Chirality of (S)-(-)-α-Methylbenzylamine

  摘要：

  DOI：

  10.1055/s-1981-29607

文献信息

• Flame-retardant aconitic acid-derived small molecules
  申请人：International Business Machines Corporation

  公开号：US10280287B2

  公开（公告）日：2019-05-07

  A flame-retardant aconitic acid-derived small molecule, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived small molecule are disclosed. The flame-retardant aconitic acid-derived small molecule can be synthesized from aconitic acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, or thioether substituents. The process for forming the flame-retardant polymer can include reacting an aconitic acid derivative with a flame-retardant phosphorus-based molecule to form a flame-retardant aconitic acid-derived small molecule, and combining the flame-retardant aconitic acid-derived small molecule with a polymer. The material in the article of manufacture can be a resin, adhesive, polymer, etc.

  公开了一种阻燃草酸衍生的小分子、形成阻燃聚合物的方法，以及包括含有阻燃草酸衍生小分子的材料的制造物品。阻燃草酸衍生的小分子可以从生物基源获得的草酸合成，并且可以具有至少一个磷酰或膦酰基团，其带有苯基、烯丙基或硫醚取代基。形成阻燃聚合物的方法可以包括将草酸衍生物与阻燃磷基分子反应以形成阻燃草酸衍生的小分子，并将阻燃草酸衍生的小分子与聚合物结合。制造物品中的材料可以是树脂、粘合剂、聚合物等。
• SORBITOL, GLUCARIC ACID, AND GLUCONIC ACID BASED FLAME-RETARDANTS
  申请人：International Business Machines Corporation

  公开号：US20190055472A1

  公开（公告）日：2019-02-21

  A flame-retardant sugar derivative, a process for forming a flame-retardant sugar derivative, and an article of manufacture comprising a flame-retardant sugar derivative are disclosed. The flame-retardant sugar derivative can be synthesized from sorbitol, gluconic acid, or glucaric acid obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety. The process for forming the flame-retardant sugar derivative can include reacting sorbitol, gluconic acid, or glucaric acid and a flame-retardant phosphorus-based molecule to form the flame-retardant sugar derivative.

  本发明公开了一种阻燃糖衍生物、制备阻燃糖衍生物的方法以及包括阻燃糖衍生物的制品。该阻燃糖衍生物可以从生物基源获得的山梨醇、葡萄糖酸或葡萄糖酸盐合成，并且可以具有至少一个磷酸酯或膦酸酯基团。制备阻燃糖衍生物的方法可以包括将山梨醇、葡萄糖酸或葡萄糖酸盐和阻燃磷基分子反应以形成阻燃糖衍生物。
• Flame-retardant vanillin-derived cross-linkers
  申请人：International Business Machines Corporation

  公开号：US10167427B2

  公开（公告）日：2019-01-01

  A flame-retardant vanillin-derived cross-linker, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived cross-linker are disclosed. The flame-retardant vanillin-derived cross-linker can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, propylene carbonate, or thioether substituents. The process for forming the flame-retardant polymer can include reacting a diol vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived cross-linker, and binding the flame-retardant vanillin-derived cross-linker to a polymer. The material in the article of manufacture can be flame-retardant, and contain flame-retardant vanillin-derived cross-linkers. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.

  本发明公开了一种阻燃香兰素衍生交联剂、一种形成阻燃聚合物的工艺，以及一种包含含有阻燃香兰素衍生交联剂的材料的制品。阻燃香兰素衍生交联剂可由生物来源的香兰素合成，并可具有至少一个苯基、烯丙基、环氧基、碳酸丙烯酯或硫醚取代基的磷酰基或膦酰基。形成阻燃聚合物的工艺可包括使二元醇香兰素衍生物和阻燃磷基分子发生反应，形成阻燃香兰素衍生交联剂，并将阻燃香兰素衍生交联剂与聚合物结合。制造物品中的材料可以是阻燃的，并含有阻燃的香兰素衍生交联剂。制造物品中的材料可包括树脂、塑料、粘合剂、聚合物等。
• Flame-retardant aconitic acid-derived cross-linkers
  申请人：International Business Machines Corporation

  公开号：US10301436B2

  公开（公告）日：2019-05-28

  A flame-retardant aconitic acid-derived cross-linker, a process for forming a flame-retardant resin, and an article of manufacture comprising a material that contains a flame-retardant aconitic acid-derived cross-linker are disclosed. The flame-retardant aconitic acid-derived cross-linker can have at least two phosphoryl or phosphonyl moieties with allyl functional groups, epoxy functional groups, propylene carbonate functional group, or functionalized thioether substituents. The process for forming the flame-retardant polymer can include forming an aconitic acid derivative, forming a phosphorus-based flame-retardant molecule, and reacting the aconitic acid derivative with the phosphorus-based flame-retardant molecule to form a flame-retardant aconitic acid-derived cross-linker, and binding the cross-linker to a polymer. The aconitic acid derivative can be synthesized from aconitic acid obtained from a bio-based source. Examples of aconitic acid derivatives include carboxysuccinic acid, 2-(hydroxymethyl)-1,4-butenediol, and 2-(hydroxymethyl)-1,4-butanediol. The article of manufacture can further comprise an electronic component.

  本发明公开了一种阻燃性乌头酸衍生交联剂、一种形成阻燃性树脂的工艺，以及一种由包含阻燃性乌头酸衍生交联剂的材料组成的制成品。阻燃性乌头酸衍生交联剂可具有至少两个带有烯丙基官能团、环氧官能团、碳酸丙烯酯官能团或官能化硫醚取代基的磷酰或膦酰基。形成阻燃聚合物的工艺可包括形成乌头酸衍生物、形成磷基阻燃分子、使乌头酸衍生物与磷基阻燃分子反应以形成阻燃的乌头酸衍生交联剂，并将交联剂与聚合物结合。乌头酸衍生物可以从生物来源的乌头酸中合成。乌头酸衍生物的例子包括羧基丁二酸、2-（羟甲基）-1,4-丁二醇和 2-（羟甲基）-1,4-丁二醇。制成品可进一步包括电子元件。
• Bondable flame-retardant vanillin-derived molecules
  申请人：International Business Machines Corporation

  公开号：US10266771B2

  公开（公告）日：2019-04-23

  A flame-retardant vanillin-derived molecule, a process for forming a flame-retardant resin, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived molecule are disclosed. The flame-retardant vanillin-derived molecule can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, propylene carbonate, or thioether substituents. The process for forming the flame-retardant resin can include reacting a vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived molecule, and binding the flame-retardant vanillin-derived molecule to a resin. The flame-retardant vanillin-derived molecules can also be bound to polymers. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived molecules. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.

  本发明公开了一种阻燃香兰素衍生分子、一种形成阻燃树脂的工艺以及一种由包含阻燃香兰素衍生分子的材料组成的制造品。阻燃香兰素衍生分子可由从生物来源获得的香兰素合成，可具有至少一个苯基、烯丙基、环氧基、碳酸丙烯酯或硫醚取代基的磷酰或膦酰基。形成阻燃树脂的工艺可包括使香兰素衍生物和阻燃磷基分子发生反应，形成阻燃香兰素衍生分子，并将阻燃香兰素衍生分子与树脂结合。阻燃香兰素衍生分子也可以与聚合物结合。制造物品中的材料可以是阻燃的，并含有阻燃香兰素衍生分子。制造物品中的材料可包括树脂、塑料、粘合剂、聚合物等。