bis(thiosaccharinato)bis(benzimidazole)cadmium(II) | 914459-72-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: bis(thiosaccharinato)bis(benzimidazole)cadmium(II)
• CAS: 914459-72-6
• 化学式: CH₄O*C₂₈H₂₀CdN₆O₄S₄
• 分子量: 777.221
• InChiKey: HZCPCZWXIMACAK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯并咪唑 、 甲醇 、 1,2-苯异噻唑-3-(2H)-硫酮-1,1-二氧化物 、 cadmium(II) nitrate tetrhydrate 以 甲醇 为溶剂， 生成 bis(thiosaccharinato)bis(benzimidazole)cadmium(II)
  参考文献：
  名称：

  Structural and spectroscopic characterization of bis(thiosaccharinato)bis(benzimidazole)cadmium(II)

  摘要：

  The crystal structure of [Cd(tsac)(2)(bzim)(2)]center dot CH3OH (tsac, anion of thiosaccharine; bzim, benzimidazole) has been determined by single crystal X-ray diffractometry. It crystallizes in the triclinic space group P (1) over bar with Z = 2. The Cd(II) cation is in a distorted tetrahedral environment coordinated to two thiosaccharinate anions [Cd-S bond lengths of 2.5117(6) and 2.5598(6) angstrom] and two benzimidazole molecules [Cd-N lengths of 2.235(2) and 2.256(2) angstrom]. The FTIR spectrum of the complex is also recorded and briefly discussed. Some comparisons with related complexes are made. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2006.03.008