2,N-dimethyl-6-(1-methylethenyl)benzenamine | 1009368-09-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,N-dimethyl-6-(1-methylethenyl)benzenamine
• 英文别名: N,2-dimethyl-6-prop-1-en-2-ylaniline
• CAS: 1009368-09-5
• 化学式: C₁₁H₁₅N
• 分子量: 161.247
• InChiKey: DIQCQYAZCWXGEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,N-dimethyl-6-(1-methylethenyl)benzenamine 、 二碳酸二叔丁酯 在 碳酸氢钠 作用下， 以 乙腈 为溶剂， 反应 24.0h， 生成 tert-butyl methyl(2-methyl-6-(prop-1-en-2-yl)phenyl)carbamate
  参考文献：
  名称：

  Convenient Synthesis of 1,4-Dihydro-2H-3,1-benzoxazin-2-ones by Iodocyclization of t-Butyl 2-Vinylphenylcarbamate

  摘要：

  It has been found that t-butyl 2-vinylphenylcarbamate derivatives underwent iodocyclization on treatment with iodine in the presence of sodium hydrogencarbonate to afford 4-iodomethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one derivatives in generally good yields. The reduction of these 4-iodomethyl derivatives with tributyltin hydride gave the corresponding 4-methyl derivatives in good yields.

  DOI：

  10.3987/com-07-11186
• 作为产物：
  描述：

  N-[2-methyl-6-(1-methylethenyl)phenyl]formamide 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 以63%的产率得到2,N-dimethyl-6-(1-methylethenyl)benzenamine
  参考文献：
  名称：

  Convenient Synthesis of 1,4-Dihydro-2H-3,1-benzoxazin-2-ones by Iodocyclization of t-Butyl 2-Vinylphenylcarbamate

  摘要：

  It has been found that t-butyl 2-vinylphenylcarbamate derivatives underwent iodocyclization on treatment with iodine in the presence of sodium hydrogencarbonate to afford 4-iodomethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one derivatives in generally good yields. The reduction of these 4-iodomethyl derivatives with tributyltin hydride gave the corresponding 4-methyl derivatives in good yields.

  DOI：

  10.3987/com-07-11186

文献信息

• [EN] HERBICIDAL COMPOUNDS<br/>[FR] COMPOSÉS HERBICIDES
  申请人：SYNGENTA CROP PROTECTION AG

  公开号：WO2020212272A1

  公开（公告）日：2020-10-22

  The present invention relates to herbicidally active cinnolinium derivatives and formulations comprising such derivatives. The invention further extends to herbicidal mixtures comprising a cinnolinium derivative as described herein and at least one additional herbicidal active ingredient. The use of the afore-mentioned cinnolinium derivatives, formulations and/or herbicidal mixtures in controlling undesirable plant growth: in particular the use for the post-emergence control of weeds, also falls within the scope of the present invention.

  本发明涉及具有除草活性的喹啉盐衍生物和包含这种衍生物的配方。该发明还涉及包括本文所述的喹啉盐衍生物和至少一种额外除草活性成分的除草混合物。上述喹啉盐衍生物、配方和/或除草混合物在控制不良植物生长方面的应用，特别是用于事后控制杂草，也属于本发明范围内。