| 1338600-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1338600-25-1
• 化学式: C₄₂H₃₀ClMn₂N₄O₆*ClO₄
• 分子量: 931.503
• InChiKey: VPCWEPAHQRGYFQ-QSEGVIKWSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium perchlorate monohydrate 、 、 N,N'-二水杨醛缩-1,2-苯二胺 以 甲醇 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, characterization, electrochemical and magnetic studies on manganese(III) complexes involving bridging carboxylates

  摘要：

  A series of carboxylate-bridged manganese(III) complexes derived from Schiff bases obtained by the condensation of salicylaldehyde or 5-bromo-salicylaldehyde and different types of diamine have been synthesized and characterized and, in the case of [Mn-2(L1)(2)(mu-ClCH2COO)](ClO4)(1), the structure has been obtained by X-ray crystallography. The structure of 1 consists of two manganese atoms separated by 5.487(3) angstrom and bridged by a carboxylate anion. This dinuclear structural unit is linked by bridging phenoxy oxygens to adjacent dinuclear units to produce a one-dimensional chain. Cyclic voltammograms of all the compounds exhibit grossly similar features consisting of a reversible or quasi-reversible Mn-III/Mn-II reduction and a Mn-III/Mn-IV oxidation. It has been observed that bromo-substitution stabilizes the lower oxidation state in the Mn-III/Mn-II couple and destabilizes the higher oxidation state in the Mn-III/Mn-IV couple. Variable temperature magnetic susceptibility measurements of 1 show a weak antiferromagnetic interaction. The magnetic behavior is satisfactorily modeled by inclusion of zero-field splitting and an intermolecular interaction component. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.041