cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-[2-(1-cyclopenta-2,4-dien-1-ylethylideneamino)phenyl]ethanimine;iron(2+) | 213195-04-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-[2-(1-cyclopenta-2,4-dien-1-ylethylideneamino)phenyl]ethanimine;iron(2+)
• CAS: 213195-04-1
• 化学式: C₃₀H₂₈Fe₂N₂
• 分子量: 528.26
• InChiKey: FTWCMVMPWYFKAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-[2-(1-cyclopenta-2,4-dien-1-ylethylideneamino)phenyl]ethanimine;iron(2+) 、 氯化铪 以 苯 为溶剂， 以60%的产率得到cyclopenta-1,3-diene;1-cyclopenta-2,4-dien-1-yl-N-[2-(1-cyclopenta-2,4-dien-1-ylethylideneamino)phenyl]ethanimine;iron(2+);tetrachlorohafnium
  参考文献：
  名称：

  Hafnium(IV) Derivatives of Schiff Bases Derived from Acetylferrocene

  摘要：

  The reactions of Schiff bases (L), derived from the condensation of acetylferrocene with ethylenediamine, o-phenylenediamine, 4-methyl-o-phenylenediamine, 1,8-diaminonaphthalene and 2,6-diaminopyridine, with hafnium tetrachloride and bis(cyclopentadienyl)hafnium(IV) dichloride have been studied in refluxing benzene/THF. The derivatives [HfCl4(L)] and [Cp2HfCl(L)]Cl have been isolated and characterized by elemental analyses, molar conductance, UV/Vis, IR and H-1 NMR. The ligands are bidentate species and coordinate to the central hafnium ion by the two nitrogens. Suggested structures for the complexes are reported.

  DOI：

  10.1080/00945719708000217

文献信息

• Srivastava; Srivastava; Sengupta, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1998, vol. 37, # 6, p. 544 - 546
  作者：Srivastava、Srivastava、Sengupta、Pandey

  DOI：——

  日期：——