tetraamminebis(saccharinato-N)cadmium | 170129-47-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: tetraamminebis(saccharinato-N)cadmium
• CAS: 170129-47-2
• 化学式: C₁₄H₂₀CdN₆O₆S₂
• 分子量: 544.891
• InChiKey: RRTXGSKDNLXHEQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetraaquabis(o-sulfobenzimidato-N)-cadmium(II) dihydrate 、 氨 以 乙醇 为溶剂， 生成 tetraamminebis(saccharinato-N)cadmium
  参考文献：
  名称：

  Tetraamminebis(saccharinato-N)cadmium

  摘要：

  Single crystals of the title compound, [Cd(C7H4N4NO3)(2)-(NH3)(4)] were prepared from tetraaquabis(saccharinatoN)cadmium dihydrate using ammonia flux [saccharin is 1,2-benzisothiazol-3(2H)-one l,l-dioxide]. The complex displays the same geometry as the parent compound, although its packing in the solid state and hydrogenbonding network are very different as a result of the absence of the water molecules of crystallization. If exposed to air, the product becomes amorphous; several studies suggest a conversion to the parent hydrogenbonding pattern by the acquisition of water molecules from the moisture in the air.

  DOI：

  10.1107/s0108270195002903