chloroplatinum(1+);dimethyl(phenyl)phosphane;diphenylphosphinate | 209162-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloroplatinum(1+);dimethyl(phenyl)phosphane;diphenylphosphinate
• CAS: 209162-60-7
• 化学式: C₄₀H₄₂Cl₂O₄P₄Pt₂
• 分子量: 1171.73
• InChiKey: UICNVZHFYKXKAP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  8.03
• 重原子数：
  52
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  [Pt(μ-Cl)Cl(dimethylphenylphosphine)]2 、 silver(I) diphenylphosphinate 以 二氯甲烷 为溶剂， 以62%的产率得到chloroplatinum(1+);dimethyl(phenyl)phosphane;diphenylphosphinate
  参考文献：
  名称：

  Synthesis and structure of binuclear complexes of palladium and platinum containing bridging diphenylphosphinate ligand

  摘要：

  Treatment of [M2Cl2(mu-Cl)(2)(PP3)(2)] (M/PR3=Pt/PEt3, Pt/PBu3, Pt/SMe2Ph, Pt/PMePh2, Pd/PMe2Ph) with AgO2PPh2 at room temperature, gave diphenylphosphinato-bridged binuclear complexes [M2Cl2(mu-O2PPh2)(2)(PR3)(2)]. These complexes were characterized by NMR spectroscopy and elemental analysis. Crystal and molecular structure of [Pt2Cl2(mu-O2PPh2)(2)(PMe2Ph)(2)] has been determined by single crystal X-ray diffraction. The eight membered metallocyclic ring "Pt-2(O2P)(2)" has a boat conformation with Pt ... Pt separation of 3.2212(6) Angstrom. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00336-7