2,6-di-(2,2'-thienyl)-N,N'-di-(n-heptyl)-1,4,5,8-tetracarboxynaphthalenediimmide | 1221401-38-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,6-di-(2,2'-thienyl)-N,N'-di-(n-heptyl)-1,4,5,8-tetracarboxynaphthalenediimmide
• 英文别名: 2,6-di-(2,2'-thienyl)-N,N'-di-(n-heptyl)-1,4,5,8-tetracarboxynaphthalenediimide；6,13-Diheptyl-2,9-dithiophen-2-yl-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 1221401-38-2
• 化学式: C₃₆H₃₈N₂O₄S₂
• 分子量: 626.841
• InChiKey: RTCUXGUNFWCBFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  44
• 可旋转键数：
  14
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  131
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  噻吩 、 2,6-dibromonaphthalene-1,4,5,8-tetracarboxy-N,N'-di(n-heptyl)imide 在 palladium diacetate 、 potassium carbonate 、 三甲基乙酸 作用下， 以 甲苯 为溶剂， 反应 18.0h， 以85%的产率得到2,6-di-(2,2'-thienyl)-N,N'-di-(n-heptyl)-1,4,5,8-tetracarboxynaphthalenediimmide
  参考文献：
  名称：

  PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS

  摘要：

  一种制备四羧基萘二酰亚胺化合物的过程，其二取代杂环基团的一般式为（I），包括至少一种二取代的N，NI-二烷基-1,4,5,8-四羧基萘二酰亚胺与至少一种杂环基化合物反应。该四羧基萘二酰亚胺化合物二取代杂环基团可以优势地用作半导体聚合物的单体，在有机场效应晶体管（OFET）或有机薄膜晶体管（OTFT）的构造中可以优势地使用。

  公开号：

  US20150051398A1

文献信息

• [EN] PROCESS FOR THE PREPARATION OF TETRACARBOXYNAPHTHALENEDIIMIDE COMPOUNDS DISUBSTITUTED WITH HETEROARYL GROUPS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS TÉTRACARBOXYNAPHTALÈNEDIIMIDE DISUBSTITUÉS PAR DES GROUPES HÉTÉROARYLE
  申请人：ENI SPA

  公开号：WO2013140328A1

  公开（公告）日：2013-09-26

  A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,NI-dialkyl-1,4,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).

  一种制备四羧基萘二酰亚胺化合物的方法，该化合物二取代杂环基团的一般式为(I)，包括至少一种取代的N，NI-二烷基-1,4,5,8-四羧基萘二酰亚胺与至少一种杂环化合物的反应。该取代杂环基团的四羧基萘二酰亚胺化合物可以优势地用作半导体聚合物的单体，这些聚合物可以优势地用于有机场效应晶体管（OFET）或有机薄膜晶体管（OTFT）的构建中。
• US9000170B2
  申请人：——

  公开号：US9000170B2

  公开（公告）日：2015-04-07
• [EN] PHOTOACTIVE COMPOSITION WITH A HIGH MOBILITY OF THE ELECTRONIC HOLES<br/>[FR] COMPOSITION PHOTOACTIVE PRÉSENTANT UNE MOBILITÉ ÉLEVÉE DES TROUS ÉLECTRONIQUES
  申请人：ENI SPA

  公开号：WO2011144537A1

  公开（公告）日：2011-11-24

  A photoactive composition with a high mobility of the elec tronic holes, comprising: -at least one organic photoactive polymer; -at least one naphthalene diimide having general formul (I): wherein: - R1 and R2, the same or different, preferably the same, are selected from linear or branched C1-C36 alky1 groups, preferably C4-C24, optionally containing heteroatoms such as, for example, oxygen, nitrogen, sulphur; - R'1 and R'2, the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C1-C10 alkyl groups, preferably C2-C6; they are preferably a hydrogen atom. - R11 and R20, the same or different, preferably the same, are a hydrogen atom, or are selected from linear or branched C1-C16 alkyl groups, preferably C2-C10; - R3, R4, R5, R6, R7, R8, R9, R10, R12, R13, R14, R15, R16, R17, R18 and R19, the same or different, are a hydrogen atom, or are selected from linear or branched C1-C16 alkyl groups preferably C2-C10; - a, b, c, d, e, f, g, and h, the same or different, are 0 or 1, on the condition that at least one is different from zero. Said photoactive composition with a high mobility of the electronic holes, can be advantageously used in the construction of photovoltaic devices, such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, both on rigid and flexible support.