[SbPh4(dimethyl-N-trichloracetylamidophosphate-1H)] | 301197-11-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [SbPh4(dimethyl-N-trichloracetylamidophosphate-1H)]
• 英文别名: 2,2,2-trichloro-N-[dimethoxy-(tetraphenyl-lambda5-stibanyl)oxy-lambda5-phosphanylidene]acetamide；2,2,2-trichloro-N-[dimethoxy-(tetraphenyl-λ5-stibanyl)oxy-λ5-phosphanylidene]acetamide
• CAS: 301197-11-5
• 化学式: C₂₈H₂₆Cl₃NO₄PSb
• 分子量: 699.601
• InChiKey: IWHKODPVDFGSBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.67
• 重原子数：
  38
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  sodium[dimethyl-N-trichloracetylamidophosphate-1H] 、 四苯基溴化锑 以 乙腈 为溶剂， 以85%的产率得到[SbPh4(dimethyl-N-trichloracetylamidophosphate-1H)]
  参考文献：
  名称：

  Spectroscopic and crystal structure data of the alkali-, thallium (I) and onic-salts of dimethyl-N-trichloracetylamidophosphate

  摘要：

  Alkali-, thallium (1) and onic-salts of dimethyl-N-trichloracetylamidophosph ate [HL] were synthesized from non-aqueous solutions and characterized by means of X-ray diffraction, IR and H-1 NMR spectroscopy. An ionic type of metal-ligand interaction was determined in Na[L] (1), Rb[L] (2) and Tl[L] (3). Several compounds containing the tetraphenylphosphonium cation, such as PPh4[L] (4), (PPh4)2[L]Br center dot H2O (5) and (PPh4)(2)[Na4L6] (6), were obtained by an exchange reaction between PPh4Br and (1) in different molar ratios. Compound 6 may be considered as the first example of an anionic complex of an alkali element in the coordination chemistry of carbacylamidophosphates. Synthesis and investigation of [SbPh4L] (7) allowed the determination of the preferable donor center of the L- ligand (the oxygen atom of the phosphoryl group). (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.01.023