chlorodiethyltin(IV) 4-benzylpiperidine-1-carbodithioate | 1198020-08-4

• 英文名称: chlorodiethyltin(IV) 4-benzylpiperidine-1-carbodithioate
• CAS: 1198020-08-4
• 化学式: C₁₇H₂₆ClNS₂Sn
• 分子量: 462.695
• InChiKey: WVRWSYMOSPDPFI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-benzylpiperidinium 4-benzylpiperidine-1-carbodithioate 、 二乙基二氯化锡 以 甲醇 为溶剂， 以79%的产率得到chlorodiethyltin(IV) 4-benzylpiperidine-1-carbodithioate
  参考文献：
  名称：

  New dimeric, trimeric and supramolecular organotin(IV) dithiocarboxylates: Synthesis, structural characterization and biocidal activities

  摘要：

  Some new tri-, chlorodi- and diorganotin(IV) dithiocarboxylates (1-10) of 4-benzylpiperidine-1-carbodithioate ligand (L), with general formulae R3SnL {R = n-C4H9 (1), C6H11 (2), CH3 (3) and C6H5 (4)}, R2SnClL {R = n-C4H9 (5), C2H5 (7), CH3 (9)} and R2SnL2 {R = n-C4H9 (6), C2H5 (8), CH3 (10)}, have been synthesized by the reaction of organotin(IV) chlorides with the ligand-salt in the appropriate molar ratio. Elemental analysis, Raman, IR, multinuclear NMR (H-1, C-13 and Sn-119) and X-ray crystallographic studies have been undertaken to elucidate the structures of the complexes, both in solution and in solid state. Single-crystal X-ray diffraction study indicate trimeric, dimeric, supramolecular cyclic and supramolecular zig-zag chain structures for complexes 2, 4, 6 and 9, respectively. Square-pyramidal geometry is attributed to complex 9 on the basis of the tau value (0.4). A subsequent antimicrobial study indicates that the compounds are biologically active. (c) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.025