(E)-(1-Methylethylidene)bis(4,1-phenyleneoxy-2,1-ethanediyl) crotonate | 93918-95-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-(1-Methylethylidene)bis(4,1-phenyleneoxy-2,1-ethanediyl) crotonate
• 英文别名: 2-[4-[2-[4-[2-[(E)-but-2-enoyl]oxyethoxy]phenyl]propan-2-yl]phenoxy]ethyl (E)-but-2-enoate
• CAS: 93918-95-7
• 化学式: C₂₇H₃₂O₆
• 分子量: 452.5
• InChiKey: QFPJYTRPZADOBT-KQQUZDAGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  33
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

文献信息

• POLYMERIZABLE DENTAL COMPOSITION BASED ON CONDENSED SILANES
  申请人：VOCO GmbH

  公开号：US20210052469A1

  公开（公告）日：2021-02-25

  The present invention relates to novel polymerizable dental compositions comprising, (A) polysiloxanes, wherein the polysiloxanes comprise a mixture of the condensates of the three silanes (a1), (a2) and (a3) and/or a cocondensate of a mixture of the three silanes (a1), (a2) and (a3) and/or a mixture of at least two of the cocondensates (a1)/(a2), (a1)/(a3) and (a2)/(a3) and/or a mixture of the condensate of one of the three silanes (a1), (a2) or (a3) with the cocondensate of the other two silanes, (B) fillers and (C) initiators and/or catalysts and/or activators for the polymerization.

  本发明涉及一种新型可聚合的牙科组合物，包括（A）聚硅氧烷，其中聚硅氧烷包括三种硅烷（a1）、（a2）和（a3）的缩聚物混合物和/或三种硅烷（a1）、（a2）和（a3）的混合物的共缩聚物和/或至少两种共缩聚物（a1）/（a2）、（a1）/（a3）和（a2）/（a3）的混合物以及三种硅烷（a1）、（a2）或（a3）的缩聚物与其他两种硅烷的共缩聚物的混合物，（B）填料和（C）聚合的引发剂和/或催化剂和/或活性剂。
• INORGANIC-ORGANIC COMPOSITE MEDICAL MATERIAL, AND METHOD OF PRODUCING INORGANIC-ORGANIC COMPOSITE MEDICAL MATERIAL
  申请人：Sun Medical Co., Ltd.

  公开号：EP3626223A1

  公开（公告）日：2020-03-25

  An inorganic-organic composite medical material includes a two-phase co-continuous structure of an inorganic substance having open pores and an organic polymer filling the open pores, wherein the open pores have an average pore diameter of 1 nm or more and 100 nm or less, and the inorganic substance has a specific surface area of 100 m2/g or less.

  一种无机-有机复合医用材料包括由具有开放孔隙的无机物质和填充开放孔隙的有机聚合物组成的两相共存结构，其中开放孔隙的平均孔隙直径为 1 nm 或以上、100 nm 或以下，无机物质的比表面积为 100 m2/g 或以下。
• CURABLE DENTAL COMPOSITION
  申请人：Tokuyama Dental Corporation

  公开号：EP3682862A1

  公开（公告）日：2020-07-22

  A dental curable composition which comprises a radically polymerizable monomer component (A), a polymerizing catalyst (B) and an inorganic granular material (C), characterized in that: the radically polymerizable monomer component (A) contains a bifunctional monomer (A-1) represented by the following formula (α),         RP-SP1-RP     (α) where, Rp is a radically polymerizable group represented by CH2=C(R)-COO- or CH2=C(R)-CONH-, wherein R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, and SP1 is a hydrocarbon group having 5 to 15 carbon atoms, and the content of the bifunctional monomer (A-1) in the radically polymerizable monomer component (A) is 5 to 40% by mass under a condition that the content of a diluting monomer (A-2) represented by the following formula (β),         RP-SP2-RP     (β) where, Rp is as defined in the above formula (α), and SP2 is an aliphatic hydrocarbon group different from SP1, an oxygen-containing aliphatic hydrocarbon group having not less than 2 oxygen atoms, or an oxygen-containing aromatic hydrocarbon group having not less than 3 oxygen atoms, is zero or not more than 10% by mass.

  一种牙科固化组合物，由可径向聚合的单体组分（A）、聚合催化剂（B）和无机颗粒材料（C）组成，其特征在于：可径向聚合的单体组分（A）含有由下式（α）表示的双官能团单体（A-1）、 RP-SP1-RP (α) 其中，Rp 是由 CH2=C(R)-COO- 或 CH2=C(R)-CONH- 表示的可辐射聚合基团，其中 R 是氢原子或具有 1 至 3 个碳原子的烃基，SP1 是具有 5 至 15 个碳原子的烃基，双官能团单体（A-1）在可辐射聚合单体组分（A）中的含量按质量计为 5 至 40%，条件是由下式（β）表示的稀释单体（A-2）的含量、 RP-SP2-RP (β) 其中，Rp 如上式（α）所定义，SP2 是不同于 SP1 的脂肪族烃基、具有不少于 2 个氧原子的含 氧脂肪族烃基或具有不少于 3 个氧原子的含氧芳香族烃基、 质量百分比为零或不超过 10%。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MEMBER
  申请人：Hoya Lens Thailand Ltd.

  公开号：EP3816715A1

  公开（公告）日：2021-05-05

  The present invention relates to [1] a polymerizable composition for optical member containing a polymerizable component and a urethaneurea compound having a structural unit derived from tolylene diisocyanate in an amount of 0.1 to 10 parts by mass based on 100 parts by mass of a total amount of the polymerizable component; [2] a production method of an optical member, including a step of injecting the polymerizable composition of [1] into a molding die, and a step of polymerizing the polymerizable composition; and [3] a spectacle lens including a spectacle lens substrate obtained by the production method of [2].

  本发明涉及[1]一种用于光学部件的可聚合组合物，该组合物含有一种可聚合组分和一种具有从甲苯二异氰酸酯衍生的结构单元的脲化合物，以可聚合组分总量为 100 份（质量）为基准，其用量为 0.2] 一种光学部件的生产方法，包括将[1]的可聚合组合物注入模塑模具的步骤，以及使该可聚合组合物聚合的步骤；以及 [3] 一种眼镜片，包括通过[2]的生产方法获得的眼镜片基板。
• RESIN COMPOSITION FOR OPTICAL MOLDING
  申请人：Kuraray Noritake Dental Inc.

  公开号：EP3900693A1

  公开（公告）日：2021-10-27

  The present invention provides a resin composition for optical shaping that emits a weaker odor, enables easy fabrication of an object by virtue of its low viscosity, and can be made into a fabricated product having desirable toughness and water resistance when used for stereolithographic fabrication (particularly by vat stereolithography) and that is particularly suited for dental occlusal splints, mouth guards, and denture base materials. The present invention relates to a resin composition for optical shaping comprising: an α,β-unsaturated double bond group-containing compound (A) having a ring structure (a) containing a nitrogen atom; a (meth)acrylic acid ester compound (B) having a boiling point of 280°C or more at normal pressure, having a carbocyclic group, and having no nitrogen-containing heterocyclic group; a photopolymerization initiator (C); and optionally, a polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less and not comprised in the α,β-unsaturated double bond group-containing compound (A) and the (meth)acrylic acid ester compound (B), wherein the content of the polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less is 20 mass% or less relative to the total amount of polymerizable compounds comprised in the resin composition for optical shaping.

  本发明提供了一种用于光学整形的树脂组合物，该组合物散发的气味较弱，因其粘度低而易于制造物体，在用于立体光刻制造（特别是大桶立体光刻）时，可制成具有理想韧性和耐水性的制成品，特别适用于牙科咬合夹板、护齿板和义齿基底材料。本发明涉及一种用于光学塑形的树脂组合物，包括具有含氮原子的环结构 (a) 的含 α、β-不饱和双键基团的化合物 (A)；(甲基) 丙烯酸酯化合物 (B)，在常压下的沸点为 280°C 或更高，具有碳环基团，且不含含氮杂环基团；光聚合引发剂 (C)；以及可选的分子量为 500 或以下且不包含在含α，β-不饱和双键基团的化合物（A）和（甲基）丙烯酸酯化合物（B）中的多功能可聚合单体（E），其中分子量为 500 或以下的多功能可聚合单体（E）的含量占光学成型用树脂组合物中可聚合化合物总量的 20% 或以下。