ammine(2,2'-bipyridine-κ2N,N')silver(I) nitrate | 1312602-68-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: ammine(2,2'-bipyridine-κ2N,N')silver(I) nitrate
• CAS: 1312602-68-8
• 化学式: C₁₀H₁₁AgN₃*NO₃
• 分子量: 343.091
• InChiKey: RUWXFTTWEWMASV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 氨 、 silver nitrate 以 甲醇 、 水 为溶剂， 以51%的产率得到ammine(2,2'-bipyridine-κ2N,N')silver(I) nitrate
  参考文献：
  名称：

  Ammine(2,2′-bipyridine-κ²N,N′)silver(I) nitrate: a dimer formed by π–π stacking and ligand-unsupported Ag...Ag interactions

  摘要：

  Reaction of AgNO3 and 2,2'-bipyridine (bipy) under ultrasonic treatment gave the title compound, [Ag(C10H8N2)(NH3)]NO3. The crystal structure consists of dimers formed by two symmetry-related Ag-I-bipy monomers connected through intra-dimer pi-pi stacking and ligand-unsupported Ag center dot center dot center dot Ag interactions. A crystallographic C2 axis passes through the mid-point of and is perpendicular to the Ag center dot center dot center dot Ag-i(-x + 1, y, -z + 1/2) axis. In addition, each Ag I cation is coordinated by one chelating bipy ligand and one ammine ligand, giving a trigonal coordination environment capped by the symmetry-equivalent Ag atom. Molecules are assembled by Ag center dot center dot center dot Ag, pi-pi, hydrogen-bond (N-H center dot center dot center dot O and C-H center dot center dot center dot O) and weak Ag center dot center dot center dot pi interactions into a three-dimensional framework. Comparing the products synthesized under different mechanical treatments, we found that reaction conditions have a significant influence on the resulting structures. The luminescence properties of the title compound are also discussed.

  DOI：

  10.1107/s010827011000377x