cis-dimercaptobis(triphenylphosphine)platinum(II) | 37580-97-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-dimercaptobis(triphenylphosphine)platinum(II)
• 英文别名: cis-dimercaptobis(triphenylphosphine)platinum(II) C36H32P2PtS2, low pressure
• CAS: 37580-97-5；76583-22-7
• 化学式: C₃₆H₃₂P₂PtS₂
• 分子量: 785.81
• InChiKey: AINZBWBRMCNOQH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.65
• 重原子数：
  41.0
• 可旋转键数：
  8.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  2.0
• 氢受体数：
  2.0

文献信息

• The preparation and structure of methanedithiolatobis(dimethylphenylphosphine)platinum(II), (PMe₂Ph)₂Pt(S₂CH₂)
  作者：Alan Shaver、Rabin D. Lai、Peter H. Bird、Wasantha Wickramasinghe

  DOI：10.1139/v85-423

  日期：1985.9.1

  Attempts to prepare the complexes cis-L₂Pt(SH)₂, where L = PPh₃, PMePh₂, and PMePh by treatment of the appropriate dichloro complexes with NaSH in the presence of CH₂Cl₂ have resulted in the isolation of the complexes L₂Pt(S₂CH₂). The X-ray structure determination of the compound for which L = PMe₂Ph confirms the presence of the CH₂S₂²⁻ligand.

  尝试制备cis-L₂Pt(SH)₂配合物，其中L = PPh₃、PMePh₂和PMePh，通过将适当的二氯配合物与NaSH在CH₂Cl₂存在下处理，导致分离出配合物L₂Pt(S₂CH₂)。对于L = PMe₂Ph的化合物进行X射线结构测定，确认了CH₂S₂²⁻配体的存在。
• Preparation of ruthenium silanethiolato complexes and their reactions with sulfur dioxide; possible models for the activation of SO2 in the homogeneously catalyzed Claus reaction
  作者：Istvan Kovacs、Celine Pearson、Alan Shaver

  DOI：10.1016/s0022-328x(99)00678-6

  日期：2000.2

  unstable CpRu(PPh3)(SO2)SSiiPr3 (6f). However, complexes 6b–e inserted one equivalent of SO2 solely at their SSiiPr3 function to give the unstable O-silyl thiosulfito complexes CpRu(PPh3)(L)SS(O)OSiiPr3 (L=CO (8b), PMe3 (8c), P(OMe)3 (8d)) as well as CpRu(dppe)SS(O)OSiiPr3 (8e). The SH bonds of CpRu(PPh3)2SH (7a) and CpRu(dppe)SH (7b) added to PhNSO to give CpRu(PPh3)2SS(O)NHPh (9a) and CpRu(dppe)SS(O)NHPh

  通过使[CPRu（PPh 3）2（丙酮）] BF 4与NaSSi i Pr 3反应制备CPRu（PPh 3）2 SSi i Pr 3（6a）。配合物6a对取代不稳定，容易得到混合配体衍生物CPRu（PPh 3）（L）SSi i Pr 3，其中L = CO（6b），PMe 3（6c），P（OMe）3（6d），在用相应的配体处理后。CPRu（DPPE）SSi i Pr 3（图6e）从复杂获得图6a和DPPE经由CPRU的中间形成（PPH 3）（η 1 -DPPE）SSI我镨3。用一当量的SO 2处理配合物6a主要产生不稳定的CPRu（PPh 3）（SO 2）SSi i Pr 3（6f）。然而，复合物6B - ë插入一个当量的SO 2仅在它们的SSi我镨3函数，得到不稳定ø -甲硅烷基络合物thiOSulfito CPRU（PPH3）（L）SS（O）OSi i Pr 3（L = CO（8b），PMe
• Low temperature emission spectra of 2-pyridyl-substituted platinum-1,2-enedithiolates
  作者：Kelly A. Van Houten、Neil V. Blough、Robert S. Pilato

  DOI：10.1016/s0020-1693(03)00211-1

  日期：2003.9

  The emissions from the 2-pyridyl- and 2-pyridinium-substituted platinum-1,2-enedithiolate complexes, L2PtS2C2(2-pyridyl(ium))(R)} where L = PPh3, PPh2Me, PPhMe2, P(propyl)3 and L-2 = dppm, dppe, and dppp were studied in DMM (DMF-CH2Cl2-MeOH, 1:1:1, v/v/v) glasses at 77 K. All of the pyridyl-substituted complexes have an emission between 18,600 and 17,900 cm(-1) with pronounced 1200 cm(-1) vibronic structure. The lifetimes of the pyridyl-substituted complexes are 216-350 mus. The pyridinium-substituted complexes have emissions in the range of 16,600-16,100 cm(-1) with less resolved vibronic structure than their pyridyl counterparts. The lifetimes of the pyridinium-substituted complexes are 158-290 mus. The emission at 77 K from both the pyridyl- and pyridinium-substituted complexes contrasts with the room temperature studies where only selected pyridinium complexes were emissive. (C) 2003 Elsevier B.V. All rights reserved.
• Homogeneous Catalysts for Claus Chemistry: The Preparation and Structure ofcis-[(PPh3)2PtS3O], a Catalytically Active Intermediate
  作者：Alan Shaver、Mohammad El-khateeb、Anne-Marie Lebuis

  DOI：10.1002/anie.199623621

  日期：1996.11.1
• Insertion Reactions of (PPh₃)₂Pt(SR)₂ with CS₂, where R = H, CMe₃, CHMe₂, 4-C₆H₄Me; Structure of (PPh₃)Pt(SC₆H₄Me)(S₂CS-4-C₆H₄Me)
  作者：Alan Shaver、Mohammad El-khateeb、Anne-Marie Lebuis

  DOI：10.1021/ic000825+

  日期：2001.9.1

  cis-(PPh3)(2)Pt(SH)(2) reacts with CS2 to give 3, while (PPh3)(2)Pt(SR)(2) reacts to give the thiolato-thioxanthato complexes 5.