((C6H3-2,6-(C6H3-2,6-(i)Pr2)2)Mn(μ-NH2)2(NH3))2 | 1222633-88-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ((C6H3-2,6-(C6H3-2,6-(i)Pr2)2)Mn(μ-NH2)2(NH3))2
• 英文别名: azane;azanide;2-[3-[2,6-di(propan-2-yl)phenyl]benzene-2-id-1-yl]-1,3-di(propan-2-yl)benzene;manganese(2+)
• CAS: 1222633-88-6
• 化学式: C₆₀H₈₄Mn₂N₄
• 分子量: 971.23
• InChiKey: YSNFAWUDNLZVEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.38
• 重原子数：
  66
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  [Mn(C6H3-2,6-(C6H3-2,6-(i-Pr)2)2)2] 、 氨 以 正己烷 为溶剂， 以54.4%的产率得到((C6H3-2,6-(C6H3-2,6-(i)Pr2)2)Mn(μ-NH2)2(NH3))2
  参考文献：
  名称：

  Reaction of M(II) Diaryls (M = Mn or Fe) with Ammonia to Afford Parent Amido Complexes

  摘要：

  The reaction of the two-coordinate diaryls MAr'(2) (M = Mn or Fe; Ar' = C6H3-2,6-(C6H3-2,6-Pr-i(2))(2)) with excess NH3 below room temperature afforded the parent amido complexes {Ar' Mn(mu-NH2)(NH3)}, (1) and {Ar' Fe(mu-NH2)}(2) (2) in good yields. The reactions were accompanied by elimination of the arene A,1 H. Both complexes were obtained as dimers in which the metals are bridged by two NH2 ligands. The complex 1 also includes an ammonia (NH3) ligand bound to each manganese. Ammonia complexation did not occur in 2, and the metals remained three-coordinate. The metal electron configurations are high-spin and antiferromagnetically coupled.

  DOI：

  10.1021/om1000502