[μ-N2(Ru(triisopropylphosphine)(N2Me2S2))2] | 684275-99-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [μ-N2(Ru(triisopropylphosphine)(N2Me2S2))2]
• CAS: 684275-99-8
• 化学式: C₅₀H₇₈N₆P₂Ru₂S₄
• 分子量: 1155.56
• InChiKey: NKRGTQDIQMJTLB-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  2-[methyl-[2-(N-methyl-2-sulfidoanilino)ethyl]amino]benzenethiolate;molecular nitrogen;ruthenium(2+);tri(propan-2-yl)phosphane 在 Ar 作用下， 以 甲苯 为溶剂， 以75%的产率得到[μ-N2(Ru(triisopropylphosphine)(N2Me2S2))2]
  参考文献：
  名称：

  Metal thiolate complexes binding molecular nitrogen under mild conditions: [μ-N2{Ru(PiPr3)(N2Me2S2)}2], the first dinuclear example

  摘要：

  Binding N-2 to the metal sulfur cofactors of nitrogenase is considered the first step of biological N-2 fixation. In quest of low-molecular weight complexes modeling this step [mu-N-2{Ru((PPr3)-Pr-i)(N2Me2S2)}(2)] (3) was synthesized and completely characterized. Complex 3 was obtained from [Ru(N-2)((PPr3)-Pr-i)(N2Me2S2)] (1) that dissociates N-2 under reduced partial pressure of N,. Complex 1, in turn, forms from [Ru(CH3CN)((PPr3)-Pr-i)(N2Me2S2)] (2) and N-2 at standard conditions (20 degreesC, 1 bar) such that the formation of 3 corresponds with a binding of molecular nitrogen to metal thiolate complex fragments under mild conditions, not requiring abiologically strong reductants. Complex 3 forms as racemate of (R,R)-3 and (S,S)-3 enantiomers which spontaneously separate upon crystallization and could both be characterized by X-ray crystallography. Complex 3 exhibits short bonds trans to the N-2 ligand, a v(N-2) frequency (2042 cm(-1)) low in comparison with that of 1 (2113 cm(-1)) and a non-linear [Ru-NdropN-Ru] entity. The thiolate donors of 3 represent Broensted-basic sites for reversible protonations so that 3 becomes a complex suited for investigations aiming at the reduction of N-2 by nitrogenase-like coupled [2H(+)/2e(-)] transfer steps. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00008-2