bis(2,2'-bipyridine-κ2N,N')(1,10-phenanthroline-κ2N,N')ruthenium(II) tetracyanoplatinate(II) | 693221-83-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bis(2,2'-bipyridine-κ2N,N')(1,10-phenanthroline-κ2N,N')ruthenium(II) tetracyanoplatinate(II)
• CAS: 693221-83-9
• 化学式: C₄N₄Pt*C₃₂H₂₄N₆Ru
• 分子量: 892.804
• InChiKey: VHCYQRAWNIJSQR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  potassium tetracyanoplatinate(II) trihydrate 、 bis(2,2'-bipyridine-κ2N,N')(1,10-phenanthroline-κ2N,N')ruthenium(II)Cl2*7H2O 以 水 为溶剂， 生成 bis(2,2'-bipyridine-κ2N,N')(1,10-phenanthroline-κ2N,N')ruthenium(II) tetracyanoplatinate(II) 、
  参考文献：
  名称：

  Bis(2,2′-bipyridine-κ²N,N′)(1,10-phenanthroline-κ²N,N′)ruthenium(II) tetracyanoplatinate(II)

  摘要：

  In the title compound, [Ru(C10H8N2)(2)(C12H8N2)][Pt(CN)(4)], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the pi-pi stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)(4)](2-) units. Two adjacent one-dimensional chains form further stacks based on the pi-pi stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Angstrom.

  DOI：

  10.1107/s0108270103029500