nickel(2+);3-[4-[4-(1,3,5,8,11-pentazacyclotridec-3-yl)phenyl]phenyl]-1,3,5,8,11-pentazacyclotridecane;tetranitrate | 193528-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: nickel(2+);3-[4-[4-(1,3,5,8,11-pentazacyclotridec-3-yl)phenyl]phenyl]-1,3,5,8,11-pentazacyclotridecane;tetranitrate
• CAS: 193528-75-5
• 化学式: C₂₈H₄₈N₁₄Ni₂O₁₂
• 分子量: 890.156
• InChiKey: KWZLFVSCGIFROP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 三乙烯四胺 、 nickel(II) nitrate 、 联苯胺 以 甲醇 、 水 为溶剂， 以59%的产率得到nickel(2+);3-[4-[4-(1,3,5,8,11-pentazacyclotridec-3-yl)phenyl]phenyl]-1,3,5,8,11-pentazacyclotridecane;tetranitrate
  参考文献：
  名称：

  Synthesis and Characterization of bis(Macrocyclic) Complexes Based on the 13-Membered Pentaaza Unit

  摘要：

  The template condensation of triethylenetetraamine, formaldehyde and benzidine in 2:4:1 molar ratio results in new types of binuclear bis(macrocyclic) complexes, [M2LX4] [M = Mn, Co, Ni, Cu, Zn, X = Cl or NO3] in which two pentaazacyclotetradecane subunits are linked by a biphenyl group attached to an uncoordinated benzidine nitrogen atom. The complexes synthesized were characterized by IR, H-1 NMR, UV/VIS, EPR, conductivity, magnetic moments and analytical data. The observed low conductance values of all these complexes suggests their non-ionic character and that all the complexes exhibit octahedral geometry around the metal ions.

  DOI：

  10.1080/00945719708000232