tris{4-[(E)-2-(4-iodophenyl)vinyl]phenyl}amine | 1439381-53-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris{4-[(E)-2-(4-iodophenyl)vinyl]phenyl}amine
• 英文别名: 4-[(E)-2-(4-iodophenyl)ethenyl]-N,N-bis[4-[(E)-2-(4-iodophenyl)ethenyl]phenyl]aniline
• CAS: 1439381-53-9
• 化学式: C₄₂H₃₀I₃N
• 分子量: 929.42
• InChiKey: NXISENOWXDCYSZ-GZDDRBCLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.9
• 重原子数：
  46
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-[2-(4-ethynylphenyl)ethenyl]-N,N-diphenylaniline 、 tris{4-[(E)-2-(4-iodophenyl)vinyl]phenyl}amine 在 copper(l) iodide 、 四(三苯基膦)钯 、 三乙胺 作用下， 以 甲苯 为溶剂， 反应 0.25h， 以63%的产率得到
  参考文献：
  名称：

  Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers

  摘要：

  Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.

  DOI：

  10.1021/ma401085q
• 作为产物：
  描述：

  三苯胺 在 potassium tert-butylate 、 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 生成 tris{4-[(E)-2-(4-iodophenyl)vinyl]phenyl}amine
  参考文献：
  名称：

  Electrogenerated Conductive Polymers from Triphenylamine End-Capped Dendrimers

  摘要：

  Electroactive end-capped dendritic macromolecules were designed and synthesized. Their structures contain triphenylamine moieties as part of the core or dendrons. The electrogenerated films produced with these monomers behaved as conductive dendritic polymers that can be reversible charged, both in the core and in the peripheral units. The design of dendrimer structures with the introduction of systematic changes allows to establish relationships between their electro-optical properties with molecular structural parameters. The films of polymeric material hold good electrical conductivity, reversible electrochemical processes and chemical stability. The results indicate that the use of conjugated and rigid structures in dendritic macromolecules is an important factor in order to obtain electropolymeric films. This work provides a model to design starburst dendrimers capable to form electrochemically active polymers with potential applications in electronic and optoelectronic devices.

  DOI：

  10.1021/ma401085q

文献信息

• Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films
  作者：María I. Mangione、Rolando A. Spanevello、Daniela Minudri、Daniel Heredia、Luciana Fernandez、Luis Otero、Fernando Fungo

  DOI：10.1016/j.electacta.2016.04.154

  日期：2016.7

  dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of

  合成并表征了一系列周边咔唑官能化的树枝状星爆单体。完全π-共轭的树枝状大分子在Pt和铟锡氧化物电极上的电化学聚合可以生成电活性聚合物薄膜。设计树枝状聚合物时，是否将电活性中心核（三苯胺）连接到外围部分，这会影响电生成聚合物的物理化学特性。通用的电聚合方法可以生成具有良好电导率，可逆电化学过程和电致变色特性的超支化大分子薄膜。