[hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate]dichloromethyltin(IV) | 163091-22-3

• 英文名称: [hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate]dichloromethyltin(IV)
• CAS: 163091-22-3
• 化学式: C₁₉H₃₁BCl₂N₆Sn
• 分子量: 543.922
• InChiKey: WURVUHWZPKEZAP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  potassium hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate 、 三氯甲基锡 以 二氯甲烷 为溶剂， 生成 [hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate]dichloromethyltin(IV)
  参考文献：
  名称：

  Organotin(IV) polypyrazolylborates VII. Hydridotris (3,4,5-trimethyl-1 H-pyrazol-1-yl) borates. X-ray crystal structures of K(HB(3,4,5-Me3Pz)3] and [HB(3,4,5-Me3Pz)3 SnMeCl2]

  摘要：

  Tin(IV) and organotin(IV) compounds containing hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate (L(3)), [R(n)SnCl(4-n-1)L(3)] (R = Me, n = 0-2) have been synthesised and studied by NMR (H-1, C-13, Sn-119) spectroscopic techniques. The compounds are not fluxional and contain six-coordinate tin(IV) with a tridentate ligand. X-ray crystal structure of [MeSnCl(2)L(3)] is reported together with that of the parent potassium hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate, K(C18H28N6B) and comparisons are made.

  DOI：

  10.1016/0022-328x(94)05003-t