3,4,4-trimethyl-5-[1-(3,4,4,5-tetramethyl-3,4-dihydro-2H-pyrrol-2-yl)meth-(Z)-ylidene]-pyrrolidin-2-one | 1148010-62-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: 3,4,4-trimethyl-5-[1-(3,4,4,5-tetramethyl-3,4-dihydro-2H-pyrrol-2-yl)meth-(Z)-ylidene]-pyrrolidin-2-one
• 英文别名: (5Z)-3,4,4-trimethyl-5-[(3,4,4,5-tetramethylpyrrol-2-yl)methylidene]pyrrolidin-2-one
• CAS: 1148010-62-1
• 化学式: C₁₆H₂₄N₂O
• 分子量: 260.379
• InChiKey: TXCFKGNFZHAZAF-JYRVWZFOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  41.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,4,4-trimethyl-1-[3,3,4-trimethyl-5-oxopyrrolidin-(2Z)-ylidene]hexane-2,5-dione 在 氨 作用下， 以 乙醇 为溶剂， 生成 3,4,4-trimethyl-5-[1-(3,4,4,5-tetramethyl-3,4-dihydro-2H-pyrrol-2-yl)meth-(Z)-ylidene]-pyrrolidin-2-one
  参考文献：
  名称：

  A Tetracarbonyl Paal-Knorr Approach to Semicorrins

  摘要：

  A semicorrin model system was prepared via a novel twofold Paal-Knorr type cyclization of a tetracarbonyl precursor which was obtained from an aldol reaction between virtually identical partners, readily available from one and the same precursor.

  DOI：

  10.3987/com-08-s(f)54

文献信息

• A Tetracarbonyl Paal-Knorr Approach to Semicorrins
  作者：Johann Mulzer、Anna Innitzer

  DOI：10.3987/com-08-s(f)54

  日期：——

  A semicorrin model system was prepared via a novel twofold Paal-Knorr type cyclization of a tetracarbonyl precursor which was obtained from an aldol reaction between virtually identical partners, readily available from one and the same precursor.