2-(PPh2(CH2)3NCH)C6H4OH | 128210-06-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(PPh2(CH2)3NCH)C6H4OH
• 英文别名: 2-(3-Diphenylphosphanylpropyliminomethyl)phenol
• CAS: 128210-06-0
• 化学式: C₂₂H₂₂NOP
• 分子量: 347.397
• InChiKey: GDEDDIKRDCYGJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetra-n-butylammonium tetrachlorooxorhenate(V) 、 2-(PPh2(CH2)3NCH)C6H4OH 以 乙醇 为溶剂， 以44%的产率得到dichloro(2-{3'-(diphenylphosphino)propyliminomethyl}phenolato-NOP)oxorhenium(V)*0.25dichloromethane
  参考文献：
  名称：

  Banbery, Hilary J.; Hussain, Wasif; Hamor, Thomas A., Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(二苯基膦基)丙胺 、 水杨醛 在 magnesium sulfate 作用下， 以 二氯甲烷 为溶剂， 反应 20.0h， 以62%的产率得到2-(PPh2(CH2)3NCH)C6H4OH
  参考文献：
  名称：

  Syntheses and molecular structures of the tridentate phosphine ligand 2-[Ph₂P(CH₂)₃NCH]C₆H₄OH (HL) and its rhenium(V) complex [ReOCl₂L]·0.25CH₂Cl₂

  摘要：

  DOI：

  10.1039/dt9900000657

文献信息

• Synthesis and characterization of mono- and bimetallic complexes with phosphine–salicylaldimine ligands. The X-ray crystal structure of trans-PdCl2{Ph2P(CH2)3NCHC6H4-o-OH}2
  作者：Gary M. Gray、Joe M. George、Minjane Jan

  DOI：10.1016/s0020-1693(01)00298-5

  日期：2001.3

  form bimetallic complexes by reaction of these complexes with either nickel acetate or diethylzinc give incomplete reactions and mixtures of products. A bimetallic Pd(II)–Ni(II) complex has been obtained by the reaction of Ph 2 P(CH 2 ) 4 NCHC 6 H 4 - o -O} 2 Ni and Pd(cod)Cl 2 . Crystals of this complex are yellow–brown but yield a green powder when ground. NMR spectra of the complex suggest that

  M Ph 2 P（CH 2）nNCHC6 H 4-o -OH} 2（n = 3，4和M =顺式和反式-PdCl 2，顺式-PtCl 2，顺式，顺式，反式-RuCl 2（CO）2）已经通过配体与合适的金属前体的反应合成。所有络合物都是以高收率获得的，并且在所有络合物中，配体仅通过磷配位。通过使这些配合物与乙酸镍或二乙基锌反应形成双金属配合物的尝试给出了不完全的反应和产物的混合物。通过Ph 2 P（CH 2）4NCHC6 H 4-o -O} 2 Ni与Pd（cod）Cl 2的反应获得了双金属Pd（II）-Ni（II）配合物。这种复合物的晶体为黄棕色，但研磨后会产生绿色粉末。配合物的NMR光谱表明它在溶液中为单体。已经确定了反式-PdCl 2 Ph 2 P（CH 2）3NCHC6 H 4-o -OH} 2的X射线晶体结构。Pd的配位几何形状几乎是一个完美的反正方平面，包含两个膦和两个氯化物。Pd-Cl键几乎与P-CH
• Complexes of functionalised phosphine ligands. Part 1. Complexes of Fe^III, Co^III, Ni^IIand Re^Vwith tridentate Schiff bases having PNO, NNO and NNS donor sets. Crystal structures of 2-(Ph₂PC₆H₄NCH)C₆H₄OH and [Co{2-(Ph₂PC₆H₄CHN)C₆H₄O}₂][PF₆]
  作者：Jonathan R. Dilworth、Stuart D. Howe、Antony J. Hutson、John R. Miller、Jack Silver、Russell M. Thompson、Mary Harman、Michael B. Hursthouse

  DOI：10.1039/dt9940003553

  日期：——

  The Schiff bases 2-[Ph(2)P(CH2)(n)N=CH] C6H4OH (n = 3, HL(1) or 2 HL(2)), 2-(RCH=N)C6H3(OH)X-4 (R = 2-Ph(2)PC(6)H(4), X = H HL(3); R = 2-C5H4N, X = H HL(4); R = 2-C5H4N. X = Cl HL(5)) were synthesised from the appropriate amine and aldehyde. On deprotonation these all functioned as tridentate monoanionic ligands to give complexes [FeL(2)](+) and [CoL(2)]+ with Fe-III and Co-III and neutral complexes of stoichiometry NiL(2) with Ni-II. The iron complexes were examined by Mossbauer spectroscopy which indicated the presence of two iron sites in [FeL(2)(1)](+) with a spin-state equilibrium dependent on both temperature and the counter ion. The complex [FeL(2)(3)](+) showed a single iron site, again with a spin state dependent on counter ion and temperature. The crystal structures of HL(3) and [CoL(2)(3)](+) have been determined. The distortions in free HL(3) predispose it for co-ordination in a fac geometry to the Co with cis-PPh(2) groups, and the changes occurring on co-ordination are discussed in detail. Reaction of RCHO (R = 2-Ph(2)PC(6)H(4) or 2-C5H4N) with 2-aminobenzenethiol gave stable thiazoles RCHNHC(6)H(4)S-2 which did not ring open to give tridentate ligands even on reaction with base and/or metal ions.