2-Phenyl-2-phosphabicyclo[3.3.1]nonane | 581777-92-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-Phenyl-2-phosphabicyclo[3.3.1]nonane
• CAS: 581777-92-6
• 化学式: C₁₄H₁₉P
• 分子量: 218.27
• InChiKey: ZFJRRZJEOFKWAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• [EN] PRODUCTION OF OXYGENATED PRODUCTS<br/>[FR] PRODUCTION DE PRODUITS OXYGENES
  申请人：SASOL TECH PTY LTD

  公开号：WO2003068719A2

  公开（公告）日：2003-08-21

  A process for producing oxygenated products includes reacting an olefin feedstock with carbon monoxide and hydrogen at an elevated reaction temperature and at a superatmospheric reaction pressure in the presence of a hydroformylation catalyst, to produce oxygenated products. The catalyst comprises a mixture of a metal, M, where M is cobalt (Co), rhodium (Rh), ruthenium (Ru) or palladium (Pd); carbon monoxide; hydrogen; and a bicyclic tertiary phosphine. The phosphine has two cyclic structures and a ligating phosphorus atom, with the ligating phosphorus forming part of the largest ring structure of the molecule, and with fewer than two hydrocarbon substituents being present on the carbon atoms of the cyclic structures of the molecule.