Diphenyl-N,N-bis-<2-hydroxy-ethyl>-aminophosphat | 56622-86-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diphenyl-N,N-bis-<2-hydroxy-ethyl>-aminophosphat
• 英文别名: Diphenyl N,N-bis(2-hydroxyethyl)phosphoramidate；2-[diphenoxyphosphoryl(2-hydroxyethyl)amino]ethanol
• CAS: 56622-86-7
• 化学式: C₁₆H₂₀NO₅P
• 分子量: 337.312
• InChiKey: YASQANMJEFBRAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  79.2
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  Diphenyl-N,N-bis-<2-(methylsulfonyloxy)-ethyl>-aminophosphat 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 生成 Diphenyl-N,N-bis-<2-hydroxy-ethyl>-aminophosphat
  参考文献：
  名称：

  N,N-双[2-(甲磺酰氧基)乙基]氨基磷酸二芳基酯在酸性和碱性溶液中的水解

  摘要：

  混合并保持20-22℃的温度，混合物用35ml稀盐酸(i:i)酸化至刚果的酸性反应，然后将烧瓶的内容物搅拌2小时。分离酸性水层，苯层用小份水洗涤两次，与主要水溶液合并。然后在搅拌和20-22℃的温度下，在新鲜的50ml苯下用固体碳酸钾将盐酸槟榔碱水溶液碱化为酚酞。苯萃取液在水浴上减压蒸发。真空分级残余物，收集bp 80-82~(5 mm)的级分。以III计算，IV的产率为42.2%。

  DOI：

  10.1007/bf00760391

文献信息

• Varnish, shaped item, electrical insulating film, laminate, flame retardant slurry and process for producing flame retardant particles and varnish
  申请人：Uchida Daisuke

  公开号：US20050159509A1

  公开（公告）日：2005-07-21

  The invention provides a varnish that contains an insulting resin, a curing agent, a flame retardant, and an organic solvent. The flame retardant comprises flame retardant particles surface treated with at least one surface treatment agent selected from the group consisting of a phosphorus compound soluble in an organic solvent, an organosilicon compound and a dispersant having a carboxyl group. A formed material is obtained by applying and drying the varnish on a substrate. A multilayer structure is obtained by forming on a substrate having a conductor circuit layer an electrical insulation layer obtained by curing the formed material obtained from the varnish.
• Hydrolysis of diaryl N,N-bis[2-(methylsulfonyloxy)ethyl]aminophosphates in acidic and alkaline solution
  作者：I. P. Titarenko、L. D. Protsenko

  DOI：10.1007/bf00760391

  日期：1976.11

  and with mixing and maintaining a temperature of 20-22~ the mixture was acidified with 35 ml of dilute hydrochloric acid (i:i) to an acidic reaction to Congo, after which the contents of the flask were stirred for 2 h. The acidic aqueous layer was separated and the benzene layer was washed twice with small portions of water, which were combined with the main aqueous solution. Then with stirring and

  混合并保持20-22℃的温度，混合物用35ml稀盐酸(i:i)酸化至刚果的酸性反应，然后将烧瓶的内容物搅拌2小时。分离酸性水层，苯层用小份水洗涤两次，与主要水溶液合并。然后在搅拌和20-22℃的温度下，在新鲜的50ml苯下用固体碳酸钾将盐酸槟榔碱水溶液碱化为酚酞。苯萃取液在水浴上减压蒸发。真空分级残余物，收集bp 80-82~(5 mm)的级分。以III计算，IV的产率为42.2%。