3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecanol | 932747-90-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecanol
• 英文别名: C4F9(CH2CF2)2CH2CH2OH；3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecan-1-ol
• CAS: 932747-90-5
• 化学式: C₁₀H₉F₁₃O
• 分子量: 392.16
• InChiKey: MLRQPYHPGCTSHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecanol 在 chromium(VI) oxide 、 硫酸 、 水 作用下， 以 乙醚 、 丙酮 为溶剂， 反应 1.0h， 以69%的产率得到3,3,5,5,7,7,8,8,8-nonafluorooctanoic acid
  参考文献：
  名称：

  基于偏二氟乙烯调聚物的新型氟化表面活性剂

  摘要：

  C n F 2 n +1（VDF）x –（CH 2）p –的合成 其中n  = 2，4; x  = 2、3、4; p  = 0、1、2和VDF以及 分别代表偏二氟乙烯（VDF）和I，OH或CO 2 H的代表。首先，在各种实验条件下研究了VDF与C n F 2 n +1 –I自由基端粒化以直接形成低分子量端粒的过程：引发剂，温度和溶剂有利于C n F 2 n +1（VDF的形成） ）x I.在任何实验条件下，均观察到•C n F 2 n +1的区域选择性自由基加成自由基到VDF的亚甲基位置上。然后，在过氧化物引发剂的存在下，将这些VDF端粒进行乙烯化，同时对含VDF的碘化物反应物进行定量转化。R F（VDF）x C 2 H 4 I变成R F（VDF）C 2 H 4 OH的化学变化分为两个步骤：（i）由DMF /水的混合物（其含量为6/1导致最佳条件）；（ii）随后是碱性介质，以将R F（VDF）x

  DOI：

  10.1016/j.jfluchem.2011.06.019
• 作为产物：
  描述：

  1-Iodo-3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecane 在 硫酸 、 水 作用下， 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成 3,3,5,5,7,7,8,8,9,9,10,10,10-tridecafluorodecanol
  参考文献：
  名称：

  基于偏二氟乙烯调聚物的新型氟化表面活性剂

  摘要：

  C n F 2 n +1（VDF）x –（CH 2）p –的合成 其中n  = 2，4; x  = 2、3、4; p  = 0、1、2和VDF以及 分别代表偏二氟乙烯（VDF）和I，OH或CO 2 H的代表。首先，在各种实验条件下研究了VDF与C n F 2 n +1 –I自由基端粒化以直接形成低分子量端粒的过程：引发剂，温度和溶剂有利于C n F 2 n +1（VDF的形成） ）x I.在任何实验条件下，均观察到•C n F 2 n +1的区域选择性自由基加成自由基到VDF的亚甲基位置上。然后，在过氧化物引发剂的存在下，将这些VDF端粒进行乙烯化，同时对含VDF的碘化物反应物进行定量转化。R F（VDF）x C 2 H 4 I变成R F（VDF）C 2 H 4 OH的化学变化分为两个步骤：（i）由DMF /水的混合物（其含量为6/1导致最佳条件）；（ii）随后是碱性介质，以将R F（VDF）x

  DOI：

  10.1016/j.jfluchem.2011.06.019

文献信息

• Fluoroalkyl surfactants
  申请人：E. I. du Pont de Nemours and Company

  公开号：US07385077B1

  公开（公告）日：2008-06-10

  Surfactants of formula (I) wherein each R is independently hydrogen or a C1 to C4 alkyl group; A is independently hydrogen or —C(O)—O—B; Ro is a linear, branched or cyclic aliphatic group, or combination thereof, having from about 2 to about 100 carbon atoms, interrupted or substituted by 1 to about 50 hydrophilic groups, said hydrophilic groups selected from the group consisting of hydroxyl, amino, ether and mixtures thereof; wherein specific ratios of and bonding of hydrophilic groups to carbon atoms is required; each B is independently of specific formulae containing perfluoroalkyl and —S(CH2)t—, and m, d, n, and t are 0 or integers with specific limitations.

  化学公式（I）中的表面活性剂，其中每个R独立地是氢原子或一个C1到C4烷基基团；A独立地是氢原子或—C(O)—O—B；Ro是一个线性、支链或环状脂肪族基团，或其组合，含有大约2到大约100个碳原子，被1到大约50个亲水基团中断或取代，所述亲水基团选自羟基、氨基、醚基及其混合物；其中需要特定比例和亲水基团与碳原子的结合；每个B独立地是包含全氟烷基和—S(CH2)t—的特定配方，m、d、n和t为0或具有特定限制的整数。
• FLUORINATED ALCOHOLS
  申请人：Mclain Stephan James

  公开号：US20100004478A1

  公开（公告）日：2010-01-07

  A compound comprising Formula 5 R f OCFHCF 2 O(CH 2 CH 2 O) v —H  Formula 5 wherein R f is C c F (2c+1) ; c is 2 to about 6; and v is 2 to about 4; and a process for its preparation comprising contacting a compound of Formula 6 R f —O—CF═CF 2 Formula 6 wherein R f is C c F (2c+1) , and c is 2 to about 6, with a compound of Formula 7 HO—(CH 2 CH 2 O) v —H  Formula 7 wherein v is 2 to about 4.

  一种化合物，其化学式为5RfOCFHCF2O(CH2CH2O)v—H，其中Rf为CcF(2c+1)；c为2至约6；v为2至约4；以及一种制备该化合物的方法，包括将化合物6的化合物与化合物7接触，化合物6的化学式为Rf—O—CF═CF2，其中Rf为CcF(2c+1)，c为2至约6，化合物7的化学式为HO—(CH2CH2O)v—H，其中v为2至约4。
• FLUORINATED ESTERS
  申请人：Murphy Peter Michael

  公开号：US20100004482A1

  公开（公告）日：2010-01-07

  A compound comprising Formula 2A, 2B, or 2C (R a —O—CO—) 2 Y  Formula 2A R a —O—CO—Y—CO—O—(CH 2 CH 2 )R f Formula 2B R a —O—CO—Y—CO—O—R  Formula 2C wherein R a is the group (i) R f (CH 2 CF 2 ) d —(C g H 2g )—; (ii) R f OCF 2 CF 2 —(C g H 2g )—; (iii) R f OCFHCF 2 O(CH 2 CH 2 O) v —(C g H 2g )—; (iv) R f OCFHCF 2 O(C w H 2w )—; (v) R f OCF(CF 3 )CONH—(C g H 2g )—; or (vi) R f (CH 2 ) h [(CF 2 CF 2 ) i (CH 2 CH 2 ) j ] k ; each R f is independently C c F (2c+1) ; c is 2 to about 6; d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; Y is a linear or branched diradical having olefinic unsaturation of the formula —C e H (2e−2) — wherein e is 2 or 3; R is H or a linear or branched alkyl group C b H (2b+1) —; and b is from 1 to about 18.

  一种化合物，包括Formula 2A，2B或2C(Ra—O—CO—)2Y，其中： Formula 2A：Ra—O—CO—Y—CO—O—( )Rf Formula 2B：Ra—O—CO—Y—CO—O—R Formula 2C 其中： Ra是基团(i) Rf(CH2CF2)d—(CgH2g)—；(ii) RfOCF2CF2—(CgH2g)—；(iii) RfOCFHCF2O( O)v—(CgH2g)—；(iv) RfOCFHCF2O(CwH2w)—；(v) RfOCF(CF3)CONH—(CgH2g)—；或(vi) Rf( )h[(CF2CF2)i( )j]k；每个Rf独立地为CcF(2c+1)；c为2至约6；d为1至约3；g为1至4；v为1至约4；w为约3至约12；h为1至约6；i、j和k每个独立地为1、2或3，或它们的混合；但vi中的碳原子总数约为8至约22；Y是具有烯烃不饱和度的线性或支链二元基，其化学式为—CeH(2e−2)—，其中e为2或3；R为H或线性或支链烷基CbH(2b+1)—；b为1至约18。
• Fluoropolymer compositions and method of use
  申请人：Peng Sheng

  公开号：US20080202384A1

  公开（公告）日：2008-08-28

  A composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a monomer, or mixture of monomers, of formula (I): R f —(CH 2 CF 2 ) q (CH 2 CH 2 ) r -Z-C(O)—C(R)═CH 2 (I) wherein q and r are each independently integers of 1 to 3; R f is a linear or branched perfluoroalkyl group having 2 to 6 carbon atoms; Z is —O—, —NR 1 — or —S—; R is hydrogen, Cl, F or CH 3 ; R 1 is hydrogen, or a C 1 to C 4 alkyl; and (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of 6 to 18 carbons; or (ii) a monomer of formula (II): (R 2 ) 2 N—R 3 —O—C(O)—C(R)═CH 2 (II) wherein R is as defined above; each R 2 is independently a C 1 to C 4 alkyl; and R 3 is a divalent linear or branched C 1 to C 4 alkylene; and wherein the nitrogen is from about 40% to 100% salinized; or (iii) a mixture thereof; said composition providing oil repellency, water repellency, and stain resistance to substrates contacted therewith; and a method for treating substrates with such copolymer compositions; are disclosed.

  本发明涉及一种组合物，其中单体按重量百分比共聚合，其中：(a)约20％至约95％的单体或单体混合物，其化学式为(I)：Rf—(CH2CF2)q( )r-Z-C(O)—C(R)═ (I)，其中inq和r分别是1至3的整数；Rf是具有2至6个碳原子的线性或支链全氟烷基；Z是—O—，—NR1—或—S—；R是氢、氯、氟或CH3；R1是氢或C1至C4烷基；以及(b)约5％至约80％的至少一种：(i)具有6至18个碳原子的线性、支链或环状烷基的烷基(甲基)丙烯酸酯单体；或(ii)化学式(II)的单体：(R2)2N—R3—O—C(O)—C(R)═ (II)，其中R如上所定义；每个R2独立地是C1至C4烷基；R3是双价的线性或支链C1至C4亚烷基；其中氮的盐化程度为约40％至100％；或(iii)其混合物；所述组合物使与其接触的基材具有抗油、抗水和防污性；以及使用这种共聚物组合物处理基材的方法。
• PARTIALLY FLUORINATED SULFONATED SURFACTANTS
  申请人：Murphy Peter Michael

  公开号：US20100003737A1

  公开（公告）日：2010-01-07

  The present invention comprises a compound comprising Formula 1A, 1B, or 1C (R a —O—CO—) 2 X  Formula 1A R a —O—CO—X—CO—O—(CH 2 CH 2 )R f Formula 1B R a —O—CO—X—CO—O—R  Formula 1C wherein R a is the group R f (CH 2 CF 2 ) d —(C g H 2g )—; R f OCF 2 CF 2 —(C g H 2g )—; R f OCFHCF 2 O(CH 2 CH 2 O) v —(C g H 2g )—; R f OCFHCF 2 O(C w H 2w ); R f OCF(CF 3 )CONH—(C g H 2g ); or R f (CH 2 ) h [(CF 2 CF 2 ) i (CH 2 CH 2 ) j ] k ; R f is C c F (2c+1) ; d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; X is a linear or branched difunctional alkyl sulfonate group —C e H (2e−1) (SO 3 M)-, wherein e is 2 or 3; M is a monovalent cation selected from the group consisting of hydrogen, ammonium, alkali metal, or alkaline earth metal; R is H or a linear or branched alkyl group C b H (2b+1) —; and b is from 1 to about 18.

  本发明包括一种化合物，其包括公式1A、1B或1C(Ra—O—CO—)2X，其中：公式1A为Ra—O—CO—X—CO—O—( )Rf；公式1B为Ra—O—CO—X—CO—O—R；公式1C为Ra—O—CO—X—CO—O—(vi)，其中：R为Rf(CH2CF2)d—(CgH2g)—、RfOCF2CF2—(CgH2g)—、RfOCFHCF2O( O)v—(CgH2g)—、RfOCFHCF2O(CwH2w)、RfOCF(CF3)CONH—(CgH2g)或Rf( )h[(CF2CF2)i( )j]k；Rf为CcF(2c+1)；d为1至约3；g为1至4；v为1至约4；w为约3至约12；h为1至约6；i、j和k各自独立地为1、2或3，或其混合物；所述(vi)中的碳原子总数为约8至约22；X为线性或支链双官能团烷基磺酸盐基——CeH(2e−1)(SO3M)-，其中e为2或3；M为从氢、铵、碱金属或碱土金属中选择的一价阳离子；R为H或线性或支链烷基CbH(2b+1)—；b为1至约18。