Visible Light Enhanced Selective Reductive Elimination of a Methylmanganese Complex from a Heterodinuclear Dimethylphenyl(4,4′-di-tert-butyl-2,2′-bipyridine)platinum−Pentacarbonylmanganese Complex
摘要:
Novel visible light induced reductive elimination of a heterodinuclear triorganoplatinum-manganese complex, ((t)Bu(2)bpy)Me2PhPt-Mn(CO)(5), gives a methylmanganese complex. MnMe(CO)(5), and a methylphenylplatinum complex, PtMePh((t)Bu(2)bpy).