4-(N,N-bis(4-methoxy-phenyl)amino)methylbenzoyl chloride | 704914-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(N,N-bis(4-methoxy-phenyl)amino)methylbenzoyl chloride
• CAS: 704914-81-8
• 化学式: C₂₁H₁₈ClNO₃
• 分子量: 367.832
• InChiKey: MCUPLVNMOFXQNM-UHFFFAOYSA-N

物化性质

• 沸点：
  512.1±45.0 °C(Predicted)
• 密度：
  1.246±0.06 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 4-(N,N-bis(4-methoxy-phenyl)amino)methylbenzoyl chloride 、 Ir((3,5-di-tert-butylphenyl)-2,2':6',2''-terpyridine)(p-anilino-2,2':6',2''-terpyridine)(PF6)3 以 吡啶 、 水 为溶剂， 以60%的产率得到Ir((3,5-di-tert-butylphenyl)-2,2':6',2''-terpyridine)(tpy-PhNHCO-diapa)(PF6)3
  参考文献：
  名称：

  Dyads Containing Iridium(III) Bis-terpyridine as Photoactive Center: Synthesis and Electron Transfer Study

  摘要：

  A series of Ir(III)-D dyads based on an iridium(III) bis-terpyridine complex as a photoactive center and tertiary amines as donor groups, as well as their individual components, have been designed to generate photoinduced charge separation. Depending on the donor group, a modular approach or a "chemistry-on-the-complex" approach has been used to prepare three different Ir(III)-D dyads. A detailed photophysical study has been performed on one Ir(III)-D dyad in which a triarylamine is linked to the iridium bis-terpyridine complex with an amido-phenyl group used as a spacer. In acetonitrile at room temperature, steady-state and time-resolved methods gave evidence of a photoinduced charge-separated state Ir--D+ with a lifetime of 70 ps. This relatively short lifetime could be due to the close proximity between the negative charge, likely localized in the bridging terpyridine, and the oxidized donor group.

  DOI：

  10.1021/ic0351038