Bis[2,6-di(propan-2-yl)phenyl]phosphane | 1622887-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis[2,6-di(propan-2-yl)phenyl]phosphane
• CAS: 1622887-11-9
• 化学式: C₂₄H₃₅P
• 分子量: 354.516
• InChiKey: ANPFALVCHMGWJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Bis[2,6-di(propan-2-yl)phenyl]phosphane 在 正丁基锂 、 三氯化磷 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 1.0h， 以95%的产率得到
  参考文献：
  名称：

  通过单个P–Asπ-相互作用和环状二膦基phosph盐稳定的无环砷阳离子

  摘要：

  稳定的无环砷阳离子R 2 As +，是亚甲基亚砜的等电子类似物，与相应的阳离子相比很少见。描述了二磷a盐的第一个例子，[{（Dipp）2 P} 2 As] [Al {OC（CF 3）3 } 4 ]·1 PhMe。由于一个孤对从平面的磷中心向砷的空对位轨道的离域，该盐表现出显着的稳定性。DFT计算已探究了2中的键合。尝试合成类似的二磷phosph盐的尝试意外地产生了环状phospho盐[ cyclo -{（Mes）P} 2P（Mes）2 ] [BAr F 4 ]·CyMe通过假定的膦取代的二膦阳离子中间体的环化反应。

  DOI：

  10.1002/anie.201905922
• 作为产物：
  描述：

  2-溴-1,3-二异丙基苯 在 正丁基锂 、 三氯化磷 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 45.0h， 生成 Bis[2,6-di(propan-2-yl)phenyl]phosphane
  参考文献：
  名称：

  通过与三角平面磷中心的pπ–pπ相互作用稳定二磷杂戊烯

  摘要：

  N杂环卡宾及其更重的同系物在一定程度上通过将N个孤对解离到碳（或更重的14号元素中心）的空对位轨道上而稳定下来。由于磷平面化的障碍很大，因此在相应的P-取代的物质中通常不存在这些相互作用。但是，通过明智地选择磷中的取代基，可以合成二磷酸亚戊二烯[（Dipp）2 P] 2 Ge，其中P中心之一是平面的（Dipp = 2,6-二异丙基苯基）。该p中心与相应短P的平面性质葛距离建议P的显著程度Ge多键特征是由于磷孤对离域到锗的空p轨道上。DFT计算支持这一命题，NBO和AIM分析与大于1的GeP键序一致。

  DOI：

  10.1002/anie.201308002

文献信息

• CARBOXYLATE METAL COMPLEX AND CATALYST FOR OLEFIN POLYMERIZATION
  申请人：Ito Shingo

  公开号：US20130158223A1

  公开（公告）日：2013-06-20

  The present invention provides a metal complex of group 10 elements of the periodic table having a carboxylate structure represented by formula (C2); a catalyst for polymerization of olefin mainly comprising the metal complex; and a method for producing polymers by homopolymerizing olefin represented by formula (1), polymerizing two or more kinds of the above olefin, or copolymerizing olefin represented by formula (1) with polar group-containing olefin represented by formula (2) (the meaning of the symbols are as set forth in the description) using the catalyst. A metal complex of group 10 elements of the periodic table, in which all of the coordinating atoms to the metal are a hetero atom is stable and useful as a catalyst component for olefin polymerization, and can be used for a long time in homopolymerization of olefin or copolymerization of two or more kinds of olefin.

  本发明提供了一种具有由式（C2）表示的羧酸盐结构的周期表第10族元素的金属配合物；主要包括所述金属配合物的烯烃聚合催化剂；以及通过使用所述催化剂，通过将由式（1）表示的烯烃进行均聚合，聚合两种或更多种上述烯烃，或将由式（1）表示的烯烃与由式（2）表示的含极性基团的烯烃进行共聚合来生产聚合物的方法。周期表第10族元素的金属配合物，其中与金属配位的所有原子均为杂原子，稳定且可用作烯烃聚合的催化剂组分，并可在烯烃的均聚合或两种或更多种烯烃的共聚合中长时间使用。
• A Fully Phosphane-Substituted Disilene
  作者：Keith Izod、Peter Evans、Paul G. Waddell

  DOI：10.1002/anie.201701867

  日期：2017.5.8

  There is growing interest in compounds containing functionalized E=E multiple bonds (E=Si, Ge, Sn, Pb) because of their potential to exhibit novel physical and chemical properties. However, compounds containing multiple functionalizations are rare, with scarcity increasing with increasing degree of substitution. The first ditetrelene R2E=ER2 in which the E=E bond is substituted by four heteroatoms

  含有官能化的E = E多个键（E = Si，Ge，Sn，Pb）的化合物由于其具有表现出新的物理和化学性质的潜力，因此引起了越来越多的关注。但是，含有多种官能团的化合物很少见，其稀缺度随取代度的增加而增加。描述了其中E ＝ E键被四个杂原子（除了Si）取代的第一二etrelrelene R 2 E ＝ ER 2。容易从SiBr 4和[[Mes）2之间的反应中分离出四磷二甲硅烷基（Mes）2 P} 2 Si = Si P（Mes）2 } 2（7）。P] Li，后者用作牺牲还原剂。介绍了7的结构，同时使用DFT计算探查了7的键合和稳定性。
• Desolvation and aggregation of sterically demanding alkali metal diarylphosphides
  作者：Keith Izod、Peter Evans、Paul G. Waddell

  DOI：10.1039/c7dt02238g

  日期：——

  adduct [(Dipp)2P]Na(PMDETA) (3c) was prepared by treatment of 3a with PMDETA. Treatment of (Dipp)(Mes)PH or (Mes)2PH with one equivalent of n-BuLi in THF gives the complexes [(Dipp)(Mes)P]Li(THF)3 (7a) and [(Mes)2P]2Li2(THF)2(OEt2) (8a) after crystallisation from diethyl ether [Mes = 2,4,6-Me3C6H2]; crystallisation of 8a from hexane gives the alternative adduct [(Mes)2P]Li(THF)3 (8b). Exposure of 7a, 8a

  （Dipp）2 PH与一当量的n- BuLi，PhCH 2 Na或PhCH 2 K在THF中反应，得到配合物[（Dipp）2 P] Li（THF）3（2a），[（Dipp）2 P] Na（THF）2 } 2（3a）和[（Dipp）2 P] K（THF）4（4a）分别为[Dipp = 2,6-iPr 2 C 6 H 3 ]。将这些化合物暴露在真空下会产生替代的溶剂化物[（Dipp）2 P] Li（THF）2（2b），[（Dipp）2 P] Na（THF） 1.5（ 3b）和[（Dipp） 2 P] K（ 4b）；通过用PMDETA处理3a制备替代加合物[（Dipp） 2 P] Na（PMDETA）（ 3c）。用一当量的n- BuLi在THF中处理（Dipp）（Mes）PH或（Mes） 2 PH，得到配合物[（Dipp）（Mes）P] Li（THF） 3（ 7a）和[（Mes） 2 P] 2从乙醚中结晶后的Li
• PRODUCTION METHOD OF COPOLYMER OF ALLYL MONOMER CONTAINING POLAR GROUP
  申请人：Nozaki Kyoko

  公开号：US20120116036A1

  公开（公告）日：2012-05-10

  The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers including monomer units represented by formulae (3) and (4) (in the formulae, R 1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R 2 represents —OH, —OCOR 3 (R 3 represents hydrocarbon group having 1 to 5 carbon atoms), —N(R 4 ) 2 (R 4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and an allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst.
• CATALYST FOR SYNTHESIZING POLYOLEFINS
  申请人：THE UNIVERSITY OF TOKYO

  公开号：US20150099857A1

  公开（公告）日：2015-04-09

  The present invention relates to a method for producing a high-molecular-weight copolymer of polar group-containing allyl monomers comprising monomer units represented by formulae (3) and (4) (in the formulae, R 1 represents a hydrogen atom (H) or hydrocarbon group having 1 to 6 carbon atoms; R 2 represents —OH, —OCOR 3 (R 3 represents hydrocarbon group having 1 to 5 carbon atoms), —N(R 4 ) 2 (R 4 represents a hydrogen atom or hydrocarbon group having 1 to 5 carbon atoms); and n and m are a value representing the molar ratio of each of the monomer units), which has few branches and unsaturated group at the molecular end, by copolymerizing olefin and an allyl compound using a metal complex of group 10 elements in the periodic system represented by formula (I) as a catalyst. The present invention enables providing a high-molecular-weight copolymer of polar group-containing allyl monomers, which copolymer has a novel structure, is available for various applications and has been considered to be difficult to synthesize by other polymerization methods such as radical polymerization; and a method for producing the same.