[(NiC6H4COO)(bis(diphenylphosphino)propane)] | 1226969-94-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(NiC6H4COO)(bis(diphenylphosphino)propane)]
• CAS: 1226969-94-3
• 化学式: C₃₄H₃₀NiO₂P₂
• 分子量: 591.249
• InChiKey: NGSLYPXYJWTMBE-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [(NiC6H4COO)(bis(diphenylphosphino)propane)] 、 碘甲烷 以 CD₂Cl₂ 为溶剂， 生成 [NiI(C6H4COOCH3)(bis(diphenylphosphino)propane)]
  参考文献：
  名称：

  Formation of Methyl Acrylate from CO₂ and Ethylene via Methylation of Nickelalactones

  摘要：

  The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the beta-hydirde elimination and the liberation of the acrylate species.

  DOI：

  10.1021/om100060y