([Cd(terephthalate)(3-(2-pyridyl)pyrazole)]].infin. | 762244-55-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: ([Cd(terephthalate)(3-(2-pyridyl)pyrazole)]].infin.
• CAS: 762244-55-3
• 化学式: C₈H₄O₄*C₈H₇N₃*Cd
• 分子量: 421.691
• InChiKey: JVZZMZFVJRTEAE-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  ([Cd(terephthalate)(3-(2-pyridyl)pyrazole)](naphthalene)1/2].infin. 以 neat (no solvent) 为溶剂， 生成 ([Cd(terephthalate)(3-(2-pyridyl)pyrazole)]].infin.
  参考文献：
  名称：

  Novel Eclipsed 2D Cadmium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-Pyridyl)pyrazole:  Crystal Structures, Emission Properties, and Inclusion of Guest Molecules

  摘要：

  Five new eclipsed two-dimensional (2D) coordination polymers, {[Cd-2(TPT)(2)L-2](GM(1))(3/2)(H2O)}(infinity) (1) (TPT = terephthalate, L = 3-(2-pyridyl)pyrazole, GM(1) = terephthalic acid), {[Cd(TPT)L](GM(2))(H2O)(2)}infinity (2) (GM(2) = L = 3-(2-pyridyl)pyrazole), {[Cd(TPT)L](GM(3))(1/2)(H2O)}infinity (3) (GM(3) = mesitylene), {[Cd-4(TPT)(4)L-4](GM(4))(7/2)}infinity (4) (GM(4) = tetramethylbenzene), and {[Cd(TPT)L](GM(5))(1/2)}(infinity) (5) (GM(5) = naphthalene), have been synthesized and characterized by X-ray diffraction. All the five complexes take the similar eclipsed 2D open-channel framework with different guest molecules included in the cavities of their channels. TGA analysis indicates that the eclipsed open-channel frameworks are thermally stable up to 300degreesC. The porous property of the 2D framework of 5 was also investigated by the XRPD technique, which indicated that the guest molecules included in the open-channel frameworks are removable and the framework is maintained after the removal of the guest molecules. Moreover, complexes 1-5 also display strong blue emission in the solid state.

  DOI：

  10.1021/ic049625e