2,4-bis-methoxycarbonyloxy-benzoyl chloride | 50740-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-bis-methoxycarbonyloxy-benzoyl chloride
• 英文别名: Dicarbomethoxy-β-resorcinoylchlorid
• CAS: 50740-11-9
• 化学式: C₁₁H₉ClO₇
• 分子量: 288.641
• InChiKey: ZNYMGONVUTWOOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.36
• 重原子数：
  19.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  88.13
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  2,4-bis-methoxycarbonyloxy-benzoyl chloride 在 lithium aluminium tetrahydride 、 乙醚 、 苯 作用下， 生成 4-dimethylaminomethyl-resorcinol
  参考文献：
  名称：

  Mangoni, Annali di Chimica, 1958, vol. 48, p. 930,933 Anm.8,937

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4-bis-methoxycarbonyloxy-benzoic acid 在 五氯化磷 作用下， 生成 2,4-bis-methoxycarbonyloxy-benzoyl chloride
  参考文献：
  名称：

  Verticillium wilt of potato: a model of key factors related to disease severity and tuber yield in Southeastern Idaho

  摘要：

  In three years (1994, 1995, and 1996), a total of 100 commercial potato fields in southeastern Idaho were surveyed for soil variables, severity of Verticillium wilt, soil inoculum density of Verticillium dahliae and Colletotrichum coccodes, colonization of stems, root, and tubers by V. dahliae and C. coccodes, and tuber yield, size, and quality. As a generalization, factors related to soil integrity (organic matter, organic nitrogen, and increased nutrient availability) were most closely related to wilt suppression and higher tuber yields, whereas factors related to loss of soil integrity (sodium and reduced nutrient availability) were related to increased wilt and lower tuber yields. In a multiple regression analysis, three independent variables, feeder-root infections by V. dahliae, sodium content in soil, and soil organic content, were significant predictors of tuber yield. With these three factors, this model accounted for 49%, 53%, and 62% of the field variability related to total yield in 1994, 1995, and 1996, respectively. Throughout this investigation, V. dahliae root infections had the most direct effect on tuber yield, which emphasizes the importance of quantifying root infections in epidemiological studies of Verticillium wilt. Based on these results, organic matter may be one factor that can be manipulated for suppression of Verticillium wilt without reducing soil populations of the pathogen.

  DOI：

  10.1007/bf02875694