Process for the preperation of a composition comprising heterophasic propylene copolymer and talc
申请人:Saudi Basic Industries Corporation
公开号:EP2711391A1
公开(公告)日:2014-03-26
The invention relates to a Process for the preparation of a composition comprising a heterophasic propylene copolymer and talc, wherein the heterophasic propylene copolymer consists of (a) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene- α-olefin copolymer consisting of at least 70% by mass of propylene and up to 30% by mass of α-olefin, based on the total mass of the propylene-based matrix, wherein the propylene-based matrix is present in an amount of 60 to 95wt% based on the total heterophasic propylene copolymer and (b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 40 to 5wt% based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100wt%, wherein the composition has a desired melt flow index in the range of 1 to 200dg/min as measured according to ISO1133 (2.16 kg/230°C), wherein at least part of the talc is surface-modified and wherein the amount of talc in the composition is from about 0.5 to at most 5wt% based on the heterophasic propylene copolymer, comprising the step of (a) melt-mixing the heterophasic propylene copolymer with the talc and a peroxide,
wherein the amount of peroxide is chosen such that a composition comprising a heterophasic propylene copolymer and talc having the desired melt flow index is obtained.
本发明涉及一种制备包含杂相丙烯共聚物和滑石粉的组合物的工艺,其中所述杂相丙烯共聚物包括(a)丙烯基基体,其中丙烯基基体由丙烯均聚物和/或丙烯-α-烯烃共聚物组成,以丙烯基基体的总质量为基准,丙烯的质量至少占70%,α-烯烃的质量不超过30%、(b) 分散乙烯-α-烯烃共聚物、其中,分散乙烯-α-烯烃共聚物的含量为异相丙烯共聚物总量的 40 至 5wt%,异相丙烯共聚物中丙烯基基体的总量和分散乙烯-α-烯烃共聚物的总量之和为 100wt%,根据 ISO1133 测量,该组合物的理想熔体流动指数范围为 1 至 200dg/min(2.16 kg/230°C),其中至少部分滑石粉是表面改性的,组合物中滑石粉的量为异相丙烯共聚物的约 0.5%至最多 5wt%,包括以下步骤 (a) 将异相丙烯共聚物与滑石粉和过氧化物熔融混合、
其中,过氧化物的用量的选择是为了得到由具有所需熔体流动指数的杂相丙烯共聚物和滑石粉组成的组合物。