Eu(2,6-bis(N-tert-butylacetamide)pyridine-N-oxide)(NO3)3(H2O) | 906449-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Eu(2,6-bis(N-tert-butylacetamide)pyridine-N-oxide)(NO3)3(H2O)
• CAS: 906449-81-8
• 化学式: C₁₇H₂₉EuN₆O₁₃
• 分子量: 677.41
• InChiKey: QNZOHVUCORQVAQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  europium(III) nitrate hexahydrate 、 2,6-bis(N-tert-butylacetamide)pyridine-N-oxide 以 乙醇 为溶剂， 以73%的产率得到Eu(2,6-bis(N-tert-butylacetamide)pyridine-N-oxide)(NO3)3(H2O)
  参考文献：
  名称：

  Synthesis and Lanthanide Coordination Properties of New 2,6-Bis(N-tert-butylacetamide)pyridine and 2,6-Bis(N-tert-butylacetamide)pyridine-N-oxide Ligands

  摘要：

  The compound 2,6-bis(N-tert-butylacetamide) pyridine ( 2) was obtained via a Ritter synthesis, and oxidation with oxone provided the title pyridine-N-oxide (3). The compounds were characterized by spectroscopic methods, and the molecular structure of the N-oxide was determined by single-crystal X-ray diffraction methods. The coordination chemistry with Eu(NO3)(3) was examined by using 1:1 and 2:1 ligand/Eu ratios, and a single-crystal X-ray analysis for Eu(3)(NO3)(3)(H2O) was completed. The ligand 3 is found to chelate in a tridentate fashion on the Eu(III).

  DOI：

  10.1021/ic060389c