[Mn(II)(N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane(2-))] | 848443-55-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Mn(II)(N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane(2-))]
• CAS: 848443-55-0
• 化学式: C₁₁H₁₈N₄O₃*Mn
• 分子量: 309.227
• InChiKey: FTPZBXPEDWJGKZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.18
• 重原子数：
  19.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  115.79
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  [Mn(II)(N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane(2-))] 、 氧气 以 N,N-二甲基甲酰胺 为溶剂， 以60%的产率得到μ-dioxo-bis-[N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane)]dimanganese(IV)
  参考文献：
  名称：

  Synthesis and Characterization of Some New Manganese(II) Complexes, Manganese(III) Heterochelates, and µ‐Dioxo‐dimanganese(IV) Complexes Involving Tetradentate Schiff Bases

  摘要：

  Condensation of 1,3-diaminopropane-2-ol with diacetylmonoxime and acetylacetone yielded the tetradentate Schiff bases N,N'-(2-hydroxy) propylene-bis{(2-imino-3-oximino)butane} (H2L2) and N,N'-(2-hydroxy) propylene-bis(acetylacetoneimine) (H2L2), respectively. The ligands form mononuclear manganese(II) complexes of the type [Mn(II)(L-1)] (1) and [Mn(II)(L-2)] (3), which are used for the formation of the manganese(III) heterochelates of the type [Mn(III)(L)(L-L)] (where H2L = H2L1 or H2L2; L-L = anion of acetylacetone or salicylaldehyde). Cationic heterochelates of the type [Mn(L)(L-L)]ClO4 where H2L = H2L1 or H2L2 and L-L = ethylenediamine and N,N'-propylene-bis(benzaldimine) (L-3) have been synthesized by the reactions of bis(acetylacetonato)manganese(II) or bis(salicylaldehydato)manganese(H) with the preformed Schiff bases or by the reactions of [Mn(II)(L-1)] or [Mn(II)(L-2)] with L-L in absolute alcohol under reflux. Some of the complexes, synthesized here, may be used as precursors in the synthesis of higher nuclearity manganese complexes. Air oxidation of [Mn(II)(L-1)] (1) and [Mn(II)(L-2)] (3) in DMF yielded the dark-brown mu-dioxo-bis-[N,N'-(2-hydroxy)propylene-bis{(2-imino-3-oximino)butane}]dimangenese(IV) (2) and mu-dioxo-bis[N,N'-(2-hydroxy)propylenebis{(acetylacetoneimine)}]dimangenese(IV) (4) complexes, respectively. All of the complexes have been characterized with the help of elemental analyses, molar conductance values, molecular weights, magnetic moments, and spectroscopic (IR, UV-VIS, ESR) data.

  DOI：

  10.1081/sim-200026605
• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane) 以 乙醇 为溶剂， 以80%的产率得到[Mn(II)(N,N'-(2-hydroxy)propylene-bis((2-imino-3-oximino)butane(2-))]
  参考文献：
  名称：

  Synthesis and Characterization of Some New Manganese(II) Complexes, Manganese(III) Heterochelates, and µ‐Dioxo‐dimanganese(IV) Complexes Involving Tetradentate Schiff Bases

  摘要：

  Condensation of 1,3-diaminopropane-2-ol with diacetylmonoxime and acetylacetone yielded the tetradentate Schiff bases N,N'-(2-hydroxy) propylene-bis{(2-imino-3-oximino)butane} (H2L2) and N,N'-(2-hydroxy) propylene-bis(acetylacetoneimine) (H2L2), respectively. The ligands form mononuclear manganese(II) complexes of the type [Mn(II)(L-1)] (1) and [Mn(II)(L-2)] (3), which are used for the formation of the manganese(III) heterochelates of the type [Mn(III)(L)(L-L)] (where H2L = H2L1 or H2L2; L-L = anion of acetylacetone or salicylaldehyde). Cationic heterochelates of the type [Mn(L)(L-L)]ClO4 where H2L = H2L1 or H2L2 and L-L = ethylenediamine and N,N'-propylene-bis(benzaldimine) (L-3) have been synthesized by the reactions of bis(acetylacetonato)manganese(II) or bis(salicylaldehydato)manganese(H) with the preformed Schiff bases or by the reactions of [Mn(II)(L-1)] or [Mn(II)(L-2)] with L-L in absolute alcohol under reflux. Some of the complexes, synthesized here, may be used as precursors in the synthesis of higher nuclearity manganese complexes. Air oxidation of [Mn(II)(L-1)] (1) and [Mn(II)(L-2)] (3) in DMF yielded the dark-brown mu-dioxo-bis-[N,N'-(2-hydroxy)propylene-bis{(2-imino-3-oximino)butane}]dimangenese(IV) (2) and mu-dioxo-bis[N,N'-(2-hydroxy)propylenebis{(acetylacetoneimine)}]dimangenese(IV) (4) complexes, respectively. All of the complexes have been characterized with the help of elemental analyses, molar conductance values, molecular weights, magnetic moments, and spectroscopic (IR, UV-VIS, ESR) data.

  DOI：

  10.1081/sim-200026605