ethyl 2-cyano-3-[(2,6-diethylphenyl)amino]acrylate | 61097-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl 2-cyano-3-[(2,6-diethylphenyl)amino]acrylate
• 英文别名: Ethyl 2-cyano-3-(2,6-diethylanilino)prop-2-enoate；ethyl 2-cyano-3-(2,6-diethylanilino)prop-2-enoate
• CAS: 61097-07-2
• 化学式: C₁₆H₂₀N₂O₂
• 分子量: 272.347
• InChiKey: NBKWYPXIKDVYJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  62.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  trans-(bromomesityl)bis(triphenylphosphino)nickel(II) 、 ethyl 2-cyano-3-[(2,6-diethylphenyl)amino]acrylate 在 sodium bis(trimethylsilyl)amide 作用下， 以 甲苯 为溶剂， 以58%的产率得到[ethyl 2-cyano-3-[(2,6-diethylphenyl)amino]acrylatemesityl](triphenylphosphino)nickel(II)
  参考文献：
  名称：

  3-Aminoiminoacrylate, 3-Aminoacrylate, and 3-Amidoiminomalonate Complexes as Catalysts for the Dimerization of Olefins

  摘要：

  Nickel(II)-aminoacrylate, -aminoiminoacrylate, and -amidoiminomalonate complexes 1-4 are suitable precursors together with appropriate cocatalysts for the catalytic dimerization of ethylene, propylene, and alpha-olefins with short chain lengths such as 1-hexene. Suitable ligands IV-VI, VIII, X, and XII generate nickel(II) compounds 1-4 active for these catalytic dimerizations. The influence of different substituents attached to the coordinating ligand backbone is tested in the catalytic reactions. Several novel monodentate and chelate nickel(II) precursor complexes 1 and 3 were isolated and also characterized by X-ray structure analysis.

  DOI：

  10.1021/om049075s

文献信息

• 3-Aminoiminoacrylate, 3-Aminoacrylate, and 3-Amidoiminomalonate Complexes as Catalysts for the Dimerization of Olefins
  作者：Martin E. Bluhm、Cristina Folli、Daniela Pufky、Mario Kröger、Olaf Walter、Manfred Döring

  DOI：10.1021/om049075s

  日期：2005.8.1

  Nickel(II)-aminoacrylate, -aminoiminoacrylate, and -amidoiminomalonate complexes 1-4 are suitable precursors together with appropriate cocatalysts for the catalytic dimerization of ethylene, propylene, and alpha-olefins with short chain lengths such as 1-hexene. Suitable ligands IV-VI, VIII, X, and XII generate nickel(II) compounds 1-4 active for these catalytic dimerizations. The influence of different substituents attached to the coordinating ligand backbone is tested in the catalytic reactions. Several novel monodentate and chelate nickel(II) precursor complexes 1 and 3 were isolated and also characterized by X-ray structure analysis.