| 15690-42-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酰胺类
• CAS: 15690-42-3
• 化学式: C6H11MgNO
• 分子量: 137.46
• InChiKey: PPAVPUAJARUJAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Lactam-block copolymers
  申请人：AlliedSignal Inc.

  公开号：EP0202419A2

  公开（公告）日：1986-11-26

  The present invention includes a reactive elastomeric block co-oligomer; a copolymer contain- ng a lactam, a co-catalyst/coupling agent, and the elastomeric block co-oligomer; and processes to make the block co-oligomer, and the copolymer. The reactive elastomeric block co-oligomer is the reaction product of a polycarboxylic acid, and a reactive moiety which can include a reactive polyether or a reactive polysulfide. The block co-oligomer of the present invention ias been found to be useful to make a polymer containing lactam monomers, at least one coupling co-catalyst compound, and the block co-oligomer with the use of a catalyst. The present invention includes a process of forming the block co-oligomer of a polycarboxylic acid and a reactive moiety. The reactive moiety can include a reactive polyether of a reactive polysulfide. The present invention further comprises a process of forming the block co-oligomer, and the process to form the lactam-block co-oligomer copolymer.

  本发明包括一种反应性弹性嵌段共聚物；一种含有内酰胺、助催化剂/偶联剂和弹性嵌段共聚物的共聚物；以及制造嵌段共聚物和共聚物的工艺。 反应性弹性嵌段共聚物是聚羧酸和反应性分子的反应产物，反应性分子可包括反应性聚醚或反应性聚硫化物。 已发现本发明的嵌段共聚单体可用于制造含有内酰胺单体、至少一种偶联助催化剂化合物和嵌段共聚单体的聚合物，并可使用催化剂。 本发明包括一种由聚羧酸和活性基团形成嵌段共聚物的工艺。反应性分子可包括反应性聚醚和反应性多硫化物。 本发明还包括形成嵌段共聚物的工艺，以及形成内酰胺-嵌段共聚物共聚物的工艺。
• Rubber modified reaction moldable nylon-6 compositions
  申请人：Monsanto Company

  公开号：EP0232694A2

  公开（公告）日：1987-08-19

  Dispersions of core-shell polymers in caprolactam wherein the core-shell polymer comprises a crosslinked elastomer core and a hard thermoplastic shell and wherein the weight ratio of elastomer core to caprolactam is in the rnage of about 1:99 to about 40:60. Such dispersions can be combined with caprolactam polymerization initiator and caprolactam polymerization catalyst to provide rubber-modified nylon-6 polymers.

  芯壳聚合物在己内酰胺中的分散体，其中芯壳聚合物包括交联弹性体芯和硬热塑性塑料壳，弹性体芯与己内酰胺的重量比约为 1:99 至约 40:60。 此类分散体可与己内酰胺聚合引发剂和己内酰胺聚合催化剂结合使用，以提供橡胶改性尼龙-6 聚合物。
• Rubber modified reaction molded nylon-6 block copolymers
  申请人：Monsanto Company

  公开号：EP0232695A2

  公开（公告）日：1987-08-19

  Dispersions of core-shell polymers in capro­lactam solutions of telechelic polymers capable of being polymerized to form rubber-modified nylon-6 block copolymers having improved impact strength wherein the core-shell polymer comprises a cross-­linked elastomer core and a hard thermoplastic polymer shell and wherein the telechelic polymers preformed or formed in situ, are capped with lactam polymerization initiator groups.

  芯壳聚合物在己内酰胺远志聚合物溶液中的分散体，可聚合形成橡胶改性尼龙-6 嵌段共聚物，具有更高的抗冲击强度，其中芯壳聚合物包括交联弹性体芯和硬质热塑性聚合物壳，预制或就地形成的远志聚合物用内酰胺聚合引发剂基团封端。
• Fiber-reinforced composite material and process for the production thereof
  申请人：TEIJIN LIMITED

  公开号：EP0505139A1

  公开（公告）日：1992-09-23

  A process for the production of a fiber-reinforced composite material, which comprises the steps of (1) preparing a polymeric composition containing a substantially linear aromatic oligomer having a terminal aliphatic hydroxyl group, bis(acylcaprolactam) and a catalyst which promotes a ring opening-addition reaction of a hydroxyl group and a caprolactam ring, (2) melting the polymeric composition and impregnating it into a fibrous reinforcing material to form a impregnated product, and (3) heating the impregnated product up to a temperature sufficient to open the caprolactam ring while inhibiting elimination of caprolactam thereby to form, as a matrix resin, a thermoplastic copolymer having an ester group and an amide group in its main chain; and a fiber-reinforced composition material produced by the above-mentioned process.

  一种生产纤维增强复合材料的工艺，包括以下步骤 (1) 制备一种聚合物组合物，该组合物含有一种具有末端脂肪族羟基的基本线性芳香族低聚物、双（酰基己内酰胺）和一种催化剂，该催化剂可促进羟基和己内酰胺环的开环加成反应、 (2) 熔化聚合物组合物并将其浸渍到纤维增强材料中，形成浸渍产品，以及 (3) 将浸渍产品加热到足以打开己内酰胺环的温度，同时抑制己内酰胺的消除，从而形成主链上具有酯基和酰胺基的热塑性共聚物，作为基体树脂； 以及由上述工艺生产的纤维增强组合材料。
• Nylon pultrusion process
  申请人：MONSANTO EUROPE S.A.

  公开号：EP0544049A1

  公开（公告）日：1993-06-02

  Disclosed herein is a process for the reactive pultrusion of pultruded articles comprising a reinforcing material (10) and a polyamide matrix which process comprises impregnating a reinforcing material (10) with a polyamide forming reaction mixture and then pultruding the impregnated reinforcing material (10) through a die (17) while polymerizing the polyamide forming reaction mixture to form a polyamide matrix, wherein the temperature of the material being pultruded is at least about at the lower end of the melting range of the polyamide.

  本文公开了一种反应拉挤工艺，用于拉挤由增强材料（10）和聚酰胺基体组成的制品，该工艺包括用聚酰胺形成反应混合物浸渍增强材料（10），然后通过模具（17）拉挤浸渍的增强材料（10），同时聚合聚酰胺形成反应混合物以形成聚酰胺基体，其中被拉挤材料的温度至少约为聚酰胺熔化范围的下限。