trans-[Pt(5-methyltetrazolato)2(PPh3)2] | 1000788-96-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-[Pt(5-methyltetrazolato)2(PPh3)2]
• CAS: 1000788-96-4
• 化学式: C₄₀H₃₆N₈P₂Pt
• 分子量: 885.807
• InChiKey: AQHXXPAVFYVUSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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文献信息

• Microwave synthesis of mono- and bis-tetrazolato complexes via 1,3-dipolar cycloaddition of organonitriles with platinum(ii)-bound azides
  作者：Suman Mukhopadhyay、Jamal Lasri、M. Adília Januário Charmier、M. Fátima C. Guedes da Silva、Armando J. L. Pombeiro

  DOI：10.1039/b709959b

  日期：——

  [2 + 3] Cycloaddition reactions of the diazidoplatinum(II) complexes cis-[Pt(N3)2(PPh3)2] 1 and cis-[Pt(N3)2(2,2′-bipy)] 4 with organonitriles NCR 2 give the bis(tetrazolato) complexes trans-[Pt(N4CR)2(PPh3)2] 3 [R = Me (3a), Et (3b), Pr (3c), Ph (3d), 4-ClC6H4 (3e)] and cis-[Pt(N4CR)2(2,2′-bipy)] 5 [R = Me (5a), Et (5b), Pr (5c), Ph (5d)]. The reaction of cis-[Pt(N3)2(PPh3)2] 1 with propionitrile

  [2 + 3]叠氮二铂（II）配合物cis- [PT（N 3）2（PPh 3）2 ] 1和cis- [PT（N 3）2（2,2'-bipy）] 4的环加成反应含有机腈NCR 2的双（四唑酸酯）配合物反式-[PT（N 4 CR）2（PPh 3）2 ] 3 [R = Me（3a），Et（3b），Pr（3c），Ph（3d） ，四氯乙烯6H 4（3e）]和顺式-[PT（N 4 CR）2（2,2'-bipy）] 5 [R = Me（5a），Et（5b），Pr（5c），Ph（5d）] 。的反应顺式[PT（N - 3）2（PPH 3）2 ] 1与丙腈也提供，除了图3B，意想不到的混合氰基四氮杂茂络合物的反式- [PT（CN）（5- ethyltetrazolato）（PPH 3）2 ]图3b' ，其从双（四氮杂茂）的反应衍生的3B与丙腈，建议通过不寻常的氧化加成，伴随生成5-乙基-1H-四唑腈到PT I
• Kreutzer, Peter H.; Weis, Johann Ch.; Bock, Henning, Chemische Berichte, 1983, vol. 116, # 7, p. 2691 - 2707
  作者：Kreutzer, Peter H.、Weis, Johann Ch.、Bock, Henning、Erbe, Juergen、Beck, Wolfgang

  DOI：——

  日期：——
• Activation of C–CN bond of propionitrile: An alternative route to the syntheses of 5-substituted-1H-tetrazoles and dicyano-platinum(II) species
  作者：Suman Mukhopadhyay、Jamal Lasri、M. Fátima C. Guedes da Silva、M. Adília Januário Charmier、Armando J.L. Pombeiro

  DOI：10.1016/j.poly.2008.06.031

  日期：2008.9

  Reaction of trans-[Pt(N4CR)(2)(PPh3)(2)] 1 (R = Me 1a, Et 1b, Ph 1c, CH2CH2Ph 1d) with propionitrile under reflux gives trans-[Pt(CN)(2)(PPh3)(2)] 2 along with 5-substitued-1H-tetrazoles N4CR 3 (R = Me 3a, Et 3b, Ph 3c, CH2CH2Ph 3d) in moderated to good yield, respectively. Treatment of cis-[Pt(N-3)(2)(PPh3)(2)] 5 with alkynes HC equivalent to CR' 6 (R' = Ph 6a, p-MeC6H4 6b) under focused microwave irradiation leads, upon azide replacement, to the formation of the dialkynyl complexes trons-[Pt(C equivalent to CR')(2)(PPh3)(2)] 7 (R' = Ph 7a, p-MeC6H4 7b) which also furnish the dicyano-platinum complex 2 in refluxing propionitrile. In both cases, the reactions leading to the formation of 2 proceed via an unusual oxidative addition, involving NC-C bond cleavage of two propionitrile molecules, and a reductive elimination process. (C) 2008 Elsevier Ltd. All rights reserved.