[(CH(C(Me)N(2,6-(i-Pr)2C6H3))2)Ge(C(N2)SiMe3)] | 1177424-87-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(CH(C(Me)N(2,6-(i-Pr)2C6H3))2)Ge(C(N2)SiMe3)]
• CAS: 1177424-87-1
• 化学式: C₃₃H₅₀GeN₄Si
• 分子量: 603.462
• InChiKey: IJZACOQPMCORKU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(CH(C(Me)N(2,6-(i-Pr)2C6H3))2)Ge(C(N2)SiMe3)] 以 正己烷 为溶剂， 生成 [(CH(C(Me)N(2,6-(i-Pr)2C6H3))2)Ge(N(SiMe3)NC)]
  参考文献：
  名称：

  Dehydrogenation of LGeH by a Lewis N-Heterocyclic Carbene Borane Pair under the Formation of L′Ge and its Reactions with B(C₆F₅)₃ and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile

  摘要：

  Herein we report the dehydrogenation of LGeH (1) [L = CH{(CMe)(2,6-IPr2C6H3N)}(2)] by a frustrated Lewis NHC borane pair under the formation of an imidazolium borate salt (2) and the heterocyclic germylene L'Ge (3) [L' = CH{(C=CH2)(CMe)(2,6-IPr2C6H3N)(2)}]. The reaction of 3 with B(C6F5)(3) in toluene results in the formation of a zwitterion containing a germylene moiety, [B(C6F5)(3)L '' Ge] (4) [L '' = CH{(CCH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}], Subsequent treatment of 4 with 1 equiv of 1,3-di-tert-butylimidazol-2-ylidene (NHC) gives B(C6F5)(3)L"'Ge (5) [L"' = CH{(C=CH2)(CCH2B(C6F5)(3))(2,6-IPr2C6H3N)(2)}] under formation of the imidazolium cation, Moreover compound 3 reacts with trimethylsilyl diazomethane (N2CHSiMe3) to form the diazogermylene LGeC(N-2)SiMe3 (6) under C-H bond cleavage. Compound 6 slowly rearranges to the isonitriletrimethylsilyl germanium(II) amide LGeN(SiMe3)NC (6a). All compounds were characterized by microanalysis and multinuclear NMR spectroscopy. Compounds 4, 6, and 6a were unequivocally identified by single crystal X-ray structure analysis.

  DOI：

  10.1021/ic900341r
• 作为产物：
  描述：

  (HC(CMeNC-2,6-i-Pr2C6H3)2)-germanium(II) hydride 在 B(C₆F₅)3 作用下， 以 正己烷 、 甲苯 为溶剂， 生成 [(CH(C(Me)N(2,6-(i-Pr)2C6H3))2)Ge(C(N2)SiMe3)]
  参考文献：
  名称：

  Dehydrogenation of LGeH by a Lewis N-Heterocyclic Carbene Borane Pair under the Formation of L′Ge and its Reactions with B(C₆F₅)₃ and Trimethylsilyl Diazomethane: An Unprecedented Rearrangement of a Diazocompound to an Isonitrile

  摘要：

  Herein we report the dehydrogenation of LGeH (1) [L = CH{(CMe)(2,6-IPr2C6H3N)}(2)] by a frustrated Lewis NHC borane pair under the formation of an imidazolium borate salt (2) and the heterocyclic germylene L'Ge (3) [L' = CH{(C=CH2)(CMe)(2,6-IPr2C6H3N)(2)}]. The reaction of 3 with B(C6F5)(3) in toluene results in the formation of a zwitterion containing a germylene moiety, [B(C6F5)(3)L '' Ge] (4) [L '' = CH{(CCH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}], Subsequent treatment of 4 with 1 equiv of 1,3-di-tert-butylimidazol-2-ylidene (NHC) gives B(C6F5)(3)L"'Ge (5) [L"' = CH{(C=CH2)(CCH2B(C6F5)(3))(2,6-IPr2C6H3N)(2)}] under formation of the imidazolium cation, Moreover compound 3 reacts with trimethylsilyl diazomethane (N2CHSiMe3) to form the diazogermylene LGeC(N-2)SiMe3 (6) under C-H bond cleavage. Compound 6 slowly rearranges to the isonitriletrimethylsilyl germanium(II) amide LGeN(SiMe3)NC (6a). All compounds were characterized by microanalysis and multinuclear NMR spectroscopy. Compounds 4, 6, and 6a were unequivocally identified by single crystal X-ray structure analysis.

  DOI：

  10.1021/ic900341r

文献信息

• β-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and -silver(I) Complexes [LGe(Me)(CuC₆F₅)_<i>n</i>]₂ (<i>n</i> = 1, 2), LGe[C(SiMe₃)N₂]AgC₆F₅, and {LGe[C(SiMe₃)N₂](AgC₆F₅)₂}₂ (L = HC[C(Me)N-2,6-<i>i</i>Pr₂C₆H₃]₂): Synthesis and Structural Characterization
  作者：Na Zhao、Jinyuan Zhang、Ying Yang、Hongping Zhu、Yan Li、Gang Fu

  DOI：10.1021/ic300216m

  日期：2012.8.20

  of LGeMe (L = HC[C(Me)N-2,6-iPr2C6H3]2) with 0.25 or 0.5 equiv of (CuC6F5)4 gave the products [LGe(Me)CuC6F5]2 (1) and [LGe(Me)(CuC6F5)2]2 (2), respectively. In situ formed 1 reacted with 0.5 equiv of (CuC6F5)4 to give 2 on the basis of NMR (1H and 19F) spectral measurements. Conversely, 2 was converted into 1 by treatment with 2 equiv of LGeMe. Reactions of LGeC(SiMe3)N2 with 1 or 2 equiv of AgC6F5·MeCN

  LGeMe（L = HC [C（Me）N-2,6- i Pr 2 C 6 H 3 ] 2）与0.25或0.5当量的（CuC 6 F 5）4反应得到产物[LGe（Me）CuC 6 F 5 ] 2（1）和[LGe（Me）（CuC 6 F 5）2 ] 2（2）。原位形成的1与0.5当量的（CuC 6 F 5）4反应，基于NMR得到2（1H和19 F）频谱测量。相反地，2转化为1与2当量的LGeMe通过治疗。LGeC（SiMe 3）N 2与1或2当量的AgC 6 F 5 ·MeCN的反应产生了相应的化合物LGe [C（SiMe 3）N 2 ] AgC 6 F 5（3）和LGe [C（SiMe 3）N 2 ]（AgC 6 F 5）2 } 2（4）。同样，将3转换为4通过用1当量的AgC 6 F 5 ·MeCN处理，通过与2当量的LGeC（SiMe 3）N 2反应将4转化为3。X射线晶体学研究表明，1包含菱形桥接（CuC