[(η6-benzene)(η-pentamethylcyclopentadienyl)ruthenium(II)]tetrafluoroborate | 103438-20-6

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [(η6-benzene)(η-pentamethylcyclopentadienyl)ruthenium(II)]tetrafluoroborate
• 英文别名: [(C5Me5)Ru(η6-C6H6)]BF4；[Cp*Ru(η6-C6H6)]BF4；benzene;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);tetrafluoroborate
• CAS: 103438-20-6
• 化学式: BF₄*C₁₆H₂₁Ru
• 分子量: 401.217
• InChiKey: NTVDUBMBUVQKMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯(五甲基环戊二烯基)合钌(III)聚合物 、 silver tetrafluoroborate 在 苯 作用下， 以 乙醇 为溶剂， 以24%的产率得到[(η6-benzene)(η-pentamethylcyclopentadienyl)ruthenium(II)]tetrafluoroborate
  参考文献：
  名称：

  Oshima, Noriaki; Suzuki, Hiroharu; Moro-oka, Yoshihiko, Inorganic Chemistry, 1986, vol. 25, # 19, p. 3407 - 3412

  摘要：

  DOI：

文献信息

• Reactions of [Cp*Ru(H₂O)(NBD)]⁺ with Dihydrogen, Silanes, Olefins, Alkynes, and Allenes
  作者：Peng Xue、Jun Zhu、Sheng Hua Liu、Xin Huang、Weng Sang Ng、Herman H. Y. Sung、Ian D. Williams、Zhenyang Lin、Guochen Jia

  DOI：10.1021/om0600285

  日期：2006.4.1

  Formal [2+2+2] addition reactions of the NBD ligand in [Cp*Ru(H2O)(NBD)]BF4 (NBD = norbornadiene) with H2, Ph3SiH, ArCHCCH2, and RC⋮CPh were observed. In contrast, olefins such as styrene and NBD do not undergo similar [2+2+2] addition reactions with [Cp*Ru(H2O)(NBD)]BF4. [Cp*Ru(H2O)(NBD)]BF4 reacts with H2 in benzene to give [Cp*Ru(η6-C6H6)]BF4 and nortricyclene. Similarly, [Cp*Ru(H2O)(NBD)]BF4 reacts

  [CP * Ru（H 2 O）（NBD）] BF 4（NBD =降冰片二烯）中的NBD配体与H 2，Ph 3 SiH，ArCH C CH 2和RC的形式[2 + 2 + 2]形式加成反应观察到⋮CPh。相反，诸如苯乙烯和NBD的烯烃没有与[CP * Ru（H 2 O）（NBD）] BF 4进行相似的[2 + 2 + 2]加成反应。的[CP *茹（H 2 O）（NBD）] BF 4下进行反应用H 2在苯，得到的[CP *茹（η 6 -C 6 H ^ 6）] BF 4和nortricyclene。同样，[CP * Ru（H 2 O）（NBD）] BF 4的Ph起反应3的SiH，得到的[CP *茹（η 6 -C 6 H ^ 5 SIPH 2 OH）] BF 4和nortricyclene。的治疗的[CP *茹（H 2 O）（NBD）] BF 4与苯乙烯产生的[CP *茹（η 6 -C 6 H ^
• Direct synthesis of arenepentamethylcyclopentadienyl ruthenium cations from ruthenium chloride
  作者：V. S. Kaganovich、A. R. Kudinov、M. I. Rybinskaya

  DOI：10.1007/bf00952956

  日期：1986.2
• Comparative Study on the Reactivity of H₂, PhCHCH₂, and PhC⋮CMe with [Cp*Ru(H₂O)(NBD)]⁺
  作者：Sheng Hua Liu、Xin Huang、Weng Sang Ng、Ting Bin Wen、Man Fung Lo、Zhong Yuan Zhou、Ian D. Williams、Zhenyang Lin、Guochen Jia

  DOI：10.1021/om020966e

  日期：2003.3.1

  [Cp*Ru(H2O)(NBD)]BF4 reacted with H-2 in benzene to give (Cp*Ru(eta(6)-C6H6)]BF4 and nortricyclene. Like the reaction of (Cp*Ru(H2O)(NBD)]BF4 with H-2, a formal [2 + 2 + 2] homo-Diels-Alder cycloaddition of MeC=CPh to NBD occurred when [Cp*Ru(H2O)(NBD)]-BF4 was treated with MeC=CPh. In contrast, an unusual coupling product, which is formed by a formal addition of a C-H bond of styrene across one of the double bonds of NBD, was produced when [Cp*Ru(H2O)(NBD)]BF4 was treated with CH2=CHPh.