bis-triphenylphosphinetetramethylthioureato(C,S)platinum(II) nitrate | 725241-13-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-triphenylphosphinetetramethylthioureato(C,S)platinum(II) nitrate
• CAS: 725241-13-4
• 化学式: C₄₁H₄₁N₂P₂PtS*NO₃
• 分子量: 912.888
• InChiKey: FWJPBWRHTKEYLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氯仿 、 bis-triphenylphosphinetetramethylthioureato(C,S)platinum(II) nitrate 以 氯仿 为溶剂， 生成 bis-triphenylphosphinetetramethylthioureato(C,S)platinum(II) nitrate * 2 chloroform
  参考文献：
  名称：

  Activation of C–H bond by cis-[Pt(NO3)2(PPh3)2], cyclometallation of tetramethylthiourea

  摘要：

  Reaction of cis-[Pt(NO3)(2)(PPh3)(2)] with tetramethylthiourea (tmtu) affords [Pt(PPh3)(2)(tmtu*)]NO3, in which tmtu* is tetramethylthiourea deprotonated at one methyl group. An X-ray investigation has shown that tmtu* is cyclometallated with Pt-S and Pt-CH2 bonds. The likely role of dissociation of the labile nitrato ligands, to give cationic intermediates, is outlined. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.09.024
• 作为产物：
  描述：

  cis-[bis(triphenylphosphane)bis(nitrato)platinul(II)] 、 四甲基硫脲 以 氯仿 为溶剂， 生成 bis-triphenylphosphinetetramethylthioureato(C,S)platinum(II) nitrate
  参考文献：
  名称：

  Activation of C–H bond by cis-[Pt(NO3)2(PPh3)2], cyclometallation of tetramethylthiourea

  摘要：

  Reaction of cis-[Pt(NO3)(2)(PPh3)(2)] with tetramethylthiourea (tmtu) affords [Pt(PPh3)(2)(tmtu*)]NO3, in which tmtu* is tetramethylthiourea deprotonated at one methyl group. An X-ray investigation has shown that tmtu* is cyclometallated with Pt-S and Pt-CH2 bonds. The likely role of dissociation of the labile nitrato ligands, to give cationic intermediates, is outlined. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.09.024