[Cu2(C6H4(OH)CO2)4(4,4'-bipyridine)] | 752991-66-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu2(C6H4(OH)CO2)4(4,4'-bipyridine)]
• CAS: 752991-66-5；654642-17-8
• 化学式: C₃₈H₂₈Cu₂N₂O₁₂
• 分子量: 831.739
• InChiKey: DDQDLGAOMTUDIO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 [Cu2(OAc)4(H2O)2] 、 水杨酸 以 甲醇 、 水 为溶剂， 生成 [Cu2(C6H4(OH)CO2)4(4,4'-bipyridine)]
  参考文献：
  名称：

  Syntheses and crystal structures of three one-dimensional copper(II) complexes constructed by salicylate and 4,4′-bipyridine: ladder, zig-zag, and linear polymeric assembly

  摘要：

  Syntheses and crystal structures of three new compounds {trans-[Cu(Hsal)(2)(4,4'-bipy)](DMF)}(n) (1), {cis-[Cu(Hsal)(2)(4,4'-bipy)](2H(2)O)}(n) (2), and [Cu-2(Hsal)(4)(4,4'-bipy)](n) (3) are reported. These three compounds have trans-, cis-, and dimer geometries bearing a common motif [Cu(Hsal)(2)(4,4-bipy)(n)] leading to ladder, zig-zag, and linear one-dimensional (1-D) networks, respectively. The Cu...Cu distances separated by 4,4'-bipy are different in these three compounds, which leads to an extension structure in compound 3 and a compact structure in compound 2. Conformations of 4,4'-bipy ligands in these three compounds are also different. In compound I there is stacking of the bidentate salicylate and the bridging salicylate from another molecule. There is also stacking of salicylate and 4,4'-bipy from another molecule in compound 2. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00254-8