N-phenyl-4-(2-phenylpropan-2-yl)-N-[4-(2-phenylpropan-2-yl)phenyl]aniline | 259218-10-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-phenyl-4-(2-phenylpropan-2-yl)-N-[4-(2-phenylpropan-2-yl)phenyl]aniline
• CAS: 259218-10-5
• 化学式: C₃₆H₃₅N
• 分子量: 481.681
• InChiKey: YKKILMITXGJVFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  37
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘苯 、 4,4'-二(苯基异丙基)二苯胺 在 1,1'-双(二苯基膦)二茂铁 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 8.0h， 以55%的产率得到N-phenyl-4-(2-phenylpropan-2-yl)-N-[4-(2-phenylpropan-2-yl)phenyl]aniline
  参考文献：
  名称：

  一种新型快速转换近红外电致变色共轭聚合物的实验和理论研究

  摘要：

  通过Suzuki偶联方法合成了一种新的快速切换的近红外电致变色共轭螺旋桨形聚合物（PBTPAFL），该聚合物具有较低的氧化电位，其中含有二三芳基胺基。在PBTPAFL薄膜中观察到的在不同电位下的UV-NIR吸收变化是完全可逆的，并且与从原始的浅绿色到深绿色再到普鲁士蓝色的强烈颜色变化有关。还发现了电致变色特性的优异的连续循环稳定性，快速的颜色切换时间为2.58 s，漂白时间为1.76 s。与P1和P2相比，在PBTPAFL的对位引入更多的供电子丙基苯基会降低电势过程中的氧化电位并防止偶联反应。d10高于450°C在室温（25°C）下具有良好的溶解性，可溶于NMP，THF，氯仿，甲苯，二甲苯和苯等常见有机溶剂，这是由于其螺旋形结构和芴上长的烷基链所致。在此，通过实验和计算研究的结合，我们基于分子轨道理论提出了一种解释电致变色氧化行为的机理。©2010 Wiley Periodicals，Inc

  DOI：

  10.1002/pola.24104

文献信息

• Novel rapid switching and bleaching electrochromic polyimides containing triarylamine with 2-phenyl-2-isopropyl groups
  作者：Cheng-Hung Chang、Kun-Li Wang、Jyh-Chiang Jiang、Der-Jang Liaw、Kueir-Rarn Lee、Juin-Yih Lai、Kuan-Hua Lai

  DOI：10.1016/j.polymer.2010.07.023

  日期：2010.9

  A series of novel organosoluble polyimides and copolyimides with a propeller-shaped triarylamine unit were prepared from diamine and various aromatic dianhydrides via direct polycondensation. All of the polymers possessed tough, flexible, and strong films with high molecular weights. The polyimide and copolyimide films revealed electrochromic characteristics, with a color change from pale yellowish at its neutral state, to green, and finally to blue at its oxidized state, at applied potentials ranging from 0 to 1.50 V. The polyimide (lb) film exhibited switching times of 4.5 s at 1.08 Vat 424 and 877 nm and 1.9 s for fast bleaching due to a pendent substituted 2-phenyl-2-isopropyl group. Cyclic voltammetry (CV) of the polymer films showed two reversible redox couples at potentials of 0.91-0.99 V and 1.30-1.38 V. respectively. The CV results of the model compound M1 and model polyimide M2, were not a match to the oxidation peaks of polyimide lb, indicating that the contribution of the oxidation was not only from the electron removal of nitrogen atoms. (C) 2010 Elsevier Ltd. All rights reserved.
• THERMOPLASTIC RESINS STABILIZED BY BLENDS OF STERICALLY HINDERED PHENOLS,SECONDARY AMINES, AND LACTONES
  申请人：UNIROYAL CHEMICAL COMPANY, Inc.

  公开号：EP1325069B1

  公开（公告）日：2006-02-22
• Novel Polymer and Copolymer and Method of Making the Same
  申请人：LIAW Der-Jang

  公开号：US20110092657A1

  公开（公告）日：2011-04-21

  The present invention discloses a polymer and a copolymer and a method of making the same. The monomer of the polymer of the present invention includes a bi-triphenylamine functional group having a first end and a second end; a fluorene functional group bonded to the first end; and at least two phenyl isopropyl group bonded to the second end.
• US8350000B2
  申请人：——

  公开号：US8350000B2

  公开（公告）日：2013-01-08